24748-23-0

Usage

Chemical Properties

clear solution

InChI:InChI=1/C12H24O6/c1-7-10(4)13-15-11(5,8-2)17-18-12(6,9-3)16-14-10/h7-9H2,1-6H3

Synthetic route

2-Pentanone (107-87-9) + butanone (78-93-3) → 3,6,9-triethyl-3,6,9-trimethyl-[1,2,4,5,7,8]hexoxonane (24748-23-0) + 3-ethyl-3,6,9-trimethyl-6,9-di-(n-propyl)-1,2,4,5,7,8-hexaoxonane + 3,6-diethyl-3,6,9-trimethyl-9-(n-propyl)-1,2,4,5,7,8-hexaoxonane

Conditions	Yield
With sulfuric acid; dihydrogen peroxide at -1 - 1℃; for 2.25h;	A 18.9% B 5.9% C 17.6%

butanone (78-93-3) → 3,6,9-triethyl-3,6,9-trimethyl-[1,2,4,5,7,8]hexoxonane (24748-23-0)

Conditions	Yield
With sulfuric acid; dihydrogen peroxide
With sulfuric acid; dihydrogen peroxide at 0℃; for 48h;

sulfuric acid (7664-93-9) + dihydrogen peroxide (7722-84-1) + butanone (78-93-3) → 3,6,9-triethyl-3,6,9-trimethyl-[1,2,4,5,7,8]hexoxonane (24748-23-0) + peroxide

butanone (78-93-3) → 3,6,9-triethyl-3,6,9-trimethyl-[1,2,4,5,7,8]hexoxonane (24748-23-0) + methyl ethyl ketone peroxide (2780-59-8)

Conditions	Yield
Stage #1: butanone; nitric acid In 2-methylundecane; water; acetic acid at 15 - 18℃; Stage #2: With dihydrogen peroxide In 2-methylundecane; water; acetic acid at 14 - 18℃; for 1h;

3,6,9-triethyl-3,6,9-trimethyl-[1,2,4,5,7,8]hexoxonane (24748-23-0) + 4-tert-Butylstyrene (1746-23-2) → 1-((E)-But-1-enyl)-4-tert-butyl-benzene

Conditions	Yield
With iron(III) trifluoromethanesulfonate In 1,4-dioxane at 80℃; for 12h; Heck Reaction;	81%

Upstream product

• 7664-93-9 sulfuric acid 
• 7722-84-1 dihydrogen peroxide 
• 78-93-3 butanone 
• 107-87-9 2-Pentanone 

Relevant academic research and scientific papers

Selective, sensitive, and rapid analysis with lateral-flow assays based on antibody-gated dye-delivery systems: The example of triacetone triperoxide

Set them free: Brightly fluorescent indicators that are loaded into mesoporous silica nanoparticle carriers, capped with bulky antibodies, are released into the lateral flow of a test strip upon analyte arrival. Integration of the system into a rapid, simple flow test with fluorescence readout is applied for the selective and sensitive determination of the presence of triacetone triperoxide (TATP) as a prototype small-molecule analyte (see figure). Copyright

CYCLIC KETONE PEROXIDE COMPOSITION

A composition comprising at least two trimeric cyclic ketone peroxides: a trimeric cyclic methyl ethyl ketone peroxide (3MEK-cp) of formula (I) and at least one peroxide satisfying formula (II) wherein R1 through R3 are independently selected from alkyl and alkoxyalkyl groups, said groups having 2 to 5 carbon atoms, the total number of carbon plus oxygen atoms of R1+R2+R3 is in the range 7-15, and the molar ratio of 3MEK-cp to the total amount of peroxides satisfying formula (II) being in the range of from 10:90 to 80:20.

METHOD FOR THE PRODUCTION OF TRIMERIC KETONE PEROXIDE SOLUTIONS

Cyclohexanone is reacted with hydrogen peroxide in the presence of nitric acid which is used as a catalyst in a suitable solvent for the production of trimeric cyclohexanone peroxide.