247912-53-4Relevant academic research and scientific papers
Preparation of 3-trifluoromethyl-2-cycloalkenones by the oxidative rearrangement of trifluoromethylated tertiary allylic alcohols with pyridinium chlorochromate
Prakash, G.K. Surya,Tongco, Emily C.,Mathew, Thomas,Vankar, Yashwant D.,Olah, George A.
, p. 199 - 202 (2000)
Trifluoromethylated tertiary allylic alcohols, obtained from trifluoromethylation of several conjugated enones, undergo oxidative rearrangements to 3-trifluoromethyl-2-cycloalkenones with pyridinium chlorochromate in the presence of a small amount of conc
CsF-catalyzed nucleophilic trifluoromethylation of trans-enones with trimethyl(trifluoromethyl)silane: A facile synthesis of trans-α-trifluoromethyl allylic alcohols
Singh, Rajendra P.,Kirchmeier, Robert L.,Shreeve, Jean'ne M.
, p. 1047 - 1049 (2008/02/09)
(matrix presented) Reactions of trans-enones, R-C=C-COR′ (R = Ph, Me, -C=CH-CH=C-S; R′ = Ph, Me, Et, CF3) (1a-e), with TMS-CF3 in the presence of catalytic amounts of cesium fluoride (CsF) in ethylene glycol dimethyl ether led to the
One Flask Preparation of Trifluoromethylated Amides from Ketones and Trifluoromethyltrimethylsilane via Ritter Reaction with Nitriles
Tongco, Emily C.,Prakash, G.K. Surya,Olah, George A.
, p. 1193 - 1195 (2007/10/03)
Trifluoromethylated amides are prepared in a simple one-flask reaction via the Ritter reaction of the corresponding trifluoromethylated silyl ethers, which themselves are readily obtained from the starting ketones and trifluoromethyltrimethylsilane. The y
