247912-53-4Relevant articles and documents
Preparation of 3-trifluoromethyl-2-cycloalkenones by the oxidative rearrangement of trifluoromethylated tertiary allylic alcohols with pyridinium chlorochromate
Prakash, G.K. Surya,Tongco, Emily C.,Mathew, Thomas,Vankar, Yashwant D.,Olah, George A.
, p. 199 - 202 (2000)
Trifluoromethylated tertiary allylic alcohols, obtained from trifluoromethylation of several conjugated enones, undergo oxidative rearrangements to 3-trifluoromethyl-2-cycloalkenones with pyridinium chlorochromate in the presence of a small amount of conc
One Flask Preparation of Trifluoromethylated Amides from Ketones and Trifluoromethyltrimethylsilane via Ritter Reaction with Nitriles
Tongco, Emily C.,Prakash, G.K. Surya,Olah, George A.
, p. 1193 - 1195 (2007/10/03)
Trifluoromethylated amides are prepared in a simple one-flask reaction via the Ritter reaction of the corresponding trifluoromethylated silyl ethers, which themselves are readily obtained from the starting ketones and trifluoromethyltrimethylsilane. The y