248-70-4Relevant articles and documents
Synthesis of [1]benzothiopheno[2,3-b][1]benzothiophene derivatives through iodine-mediated sulfuration reaction of 1,1-diarylethylenes
Sakai, Shuta,Sato, Kazuki,Yoshida, Kazuhiro
, (2019/12/27)
Acceleration of the reaction for the synthesis of [1]benzothiopheno[2,3-b][1]benzothiophenes (BTBTs) from 1,1-diarylethylenes was accomplished by the addition of molecular iodine. Postulated intermediates 3-arylbenzo[b]thiophenes were also selectively prepared by simply changing the amount of iodine and the reaction time.
Thiones as reactive intermediates in condensations of diketones with aromatics mediated by tetraphosphorus decasulfide
Morrison, Brian J.,Musgrave, Oliver C.
, p. 2725 - 2744 (2007/10/03)
Phenanthrene-9,10-quinone and P4S10 react with phenols on being heated to give oxathiins, e.g., 9 the dioxin 22, ethers, e.g., 14 arylphenanthrenols, e.g., 10 and furanols, e.g., 17 in addition to sulfides, e.g., 26 and disulfides, e
HIGH-TEMPERATURE ORGANIC SYNTHESIS. XXII. THERMAL TRANSFORMATIONS OF EXO-CHLORINE-SUBSTITUTED TOLUENES
Voronkov, M. G.,Deryagina, E. N.,Shagun, L. G.,Vitkovskii, V. Yu.
, p. 962 - 966 (2007/10/02)
The gas-phase pyrolysis of exo-chlorine-substituted toluenes in an atmosphere of nitrogen or hydrogen sulfide was investigated.Hydrogen sulfide stimulates the thermolysis of benzyl chloride, accelerating the formation of toluene and stilbene at 430 deg C.The other reaction products are anthracene and bibenzyl.Similar compounds and also phenanthrene are formed during the pyrolysis of benzylidene chloride in an atmosphere of nitrogen or hydrogen sulfide (500 deg C).Benzotrichloride is distinguished by its high stability; its pyrolysis mainly with the formation of 1,2-dichloro-1,2-diphenylethylene is realized at temperatures above 550 deg C.With hydrogen sulfide it reacts at 400 deg C to form bibenzyl, stilbene, anthracene, phenanthrene, and thianaphtenothianaphthene.The latter is the main product in a recirculation-type system.