24815-56-3

Upstream product

• 109-01-3 1-methyl-piperazine 
• 87203-77-8 2-(3,4-dimethoxyphenyl)-1-(4-tolyl)ethyl chloride 
• 622-97-9 1-ethenyl-4-methylbenzene 
• 6380-23-0 3,4-dimethoxystyrene 
• 136114-02-8 (E)-1,2-dimethoxy-4-(2-methoxyethenyl)benzene 
• 4294-57-9 para-methylphenylmagnesium bromide 
• 3762-25-2 diethyl 4-methylbenzylphosphonate 
• 120-14-9 3,4-dimethoxy-benzaldehyde 
• 108-88-3 toluene 
• 87203-76-7 2-(3,4-dimethoxyphenyl)-1-(4-tolyl)ethanol 
• 87203-56-3 2-(3,4-dimethoxyphenyl)-1-(4-methylphenyl)ethanone 
• 10313-60-7 3,4-dimethoxyphenylacetyl chloride 

Downstream Products

• 23798-14-3 trans-1-<3,4-Dimethoxy-styryl>-4-<4-phenyl-styryl>-benzol 
• 23798-29-0 trans-1-<3,4-Dimethoxy-styryl>-4-<4-isopropyl-styryl>-benzol 
• 23798-15-4 trans-1-(3,4-Dimethoxystyryl)-4-(3,4,5-trimethoxy-styryl)-benzol 
• 23798-30-3 trans-1-(3,4-Dimethoxy-styryl)-4-(4-phenoxy-styryl)-benzol 

Relevant academic research and scientific papers

Nickel-Catalyzed system for the cross-coupling of alkenyl methyl ethers with grignard reagents under mild conditions

A nickel-catalyzed cross-coupling of alkenyl methyl ethers with Grignard reagents, under mild conditions, is described. These conditions allowed access to various stilbenes and heterocyclic stilbenic derivatives as well as to a potential anticancer agent DMU-212.

A simple access to biologically important trans-stilbenes via Ru-catalyzed cross metathesis

The cross metathesis of methoxy- or acetoxy-substituted styrenes using the Grubbs II catalyst affords unsymmetrical (mixed) E-stilbenes with astonishingly high selectivity (up to 79% yield). This approach offers a short and flexible synthesis of variously substituted stilbenes, which are derivatives or precursors of biologically important compounds such as resveratrol, piceatannol, and pinostilbene. Georg Thieme Verlag Stuttgart.