2496-21-1Relevant academic research and scientific papers
Azobenzene molecular material with photoinduced solid-liquid conversion characteristic and synthesis method and application of azobenzene molecular material
-
Paragraph 0036-0041, (2021/01/11)
The invention relates to an azobenzene molecular material with a photoinduced solid-liquid conversion characteristic and a synthesis method and application thereof. The azobenzene molecular material has a structure as shown in a formula I which is describ
Reversible Micrometer-Scale Spiral Self-Assembly in Liquid Crystalline Block Copolymer Film with Controllable Chiral Response
Yuan, Jianan,Lu, Xuemin,Li, Qingxiang,Lü, Zhiguo,Lu, Qinghua
supporting information, p. 12308 - 12312 (2021/04/26)
The spiral is a fundamental structure in nature and spiral structures with controllable handedness are of increasing interest in the design of new chiroptical materials. In this study, micrometer-scale spiral structures with reversible chirality were fabr
Branched Aggregates with Tunable Morphology via Hierarchical Self-Assembly of Azobenzene-Derived Molecular Double Brushes
Lin, Shaoliang,Qian, Hongyu,Xu, Binbin,Zhang, Ling
, p. 17707 - 17713 (2021/07/12)
Hierarchical self-assembly is one of the most effective approaches to fabricate nature-inspired materials with subtle nanostructures. We report a distinct hierarchical self-assembly process of molecular double brushes (MDBs) with each graft site carrying
CO2 /N2 Light double-stimulus-responsive surfactant and synthetic method thereof
-
Paragraph 0017; 0033; 0034, (2017/08/25)
The invention relates to a CO2/N2-light dual-stimulus-response type surfactant, and belongs to the field of colloid and interfacial chemistry. The surfactant is an azobenzene bicarbonate surfactant prepared by using 4-alkylaniline and phenol as raw materi
Containing azo phenyl the xylosides and its preparation method and application
-
Paragraph 0101-0104, (2017/05/02)
The invention belongs to the field of catalytic reaction engineering, and particularly relates to synthetic glucoside containing an azobenzene group, and application of the glucoside serving as an ultraviolet controlled-release material. The glucoside containing an azobenzene group has a structure as shown in Formula (I). The glucoside containing an azobenzene group can be used for preparation of ultraviolet sensitive liposome, and has favorable structural stability, biological targeting property, biocompatibility and in-vivo degradability.
A self-healing photoinduced-deformable material fabricated by liquid crystalline elastomers using multivalent hydrogen bonds as cross-linkers
Ni, Bin,Xie, He-Lou,Tang, Jun,Zhang, Hai-Liang,Chen, Er-Qiang
supporting information, p. 10257 - 10260 (2016/08/23)
Liquid crystalline elastomers (LCEs) using multivalent hydrogen bonds as cross-linkers were successfully fabricated, which showed both self-healing and photoinduced-deformable properties. More interestingly, this LCE could be readily molded into different
Photochromic and nonlinear optical properties of azo-functionalized POSS nanoparticles dispersed in nematic liquid crystals
Miniewicz, Andrzej,Girones, Julie,Karpinski, Pawel,Mossety-Leszczak, Beata,Galina, Henryk,Dutkiewicz, Michal
, p. 432 - 440 (2014/01/06)
It is well known that addition of a small amount of nanoparticles to liquid crystals may enhance their nonlinear optical properties. To date, in most reports, semiconductor- or metallic-core nanoparticles in LCs have been described. Here, we report on the
Micellar catalysis using a photochromic surfactant: Application to the pd-catalyzed tsuji-trost reaction in water
Billamboz, Muriel,Mangin, Floriane,Drillaud, Nicolas,Chevrin-Villette, Carole,Banaszak-Leonard, Estelle,Len, Christophe
, p. 493 - 500 (2014/04/03)
The first example of a Pd-catalyzed Tsuji-Trost reaction, applied in a photochromic micellar media under conventional heating and microwave irradiation, is reported. The surfactant activity and recycling ability were investigated and compared with those of a few commercially available surfactants. The synthetic photochromic surfactant proved to be efficient, recyclable, and versatile for Pdcatalyzed coupling reactions.
Chiral self-assembly of designed amphiphiles: Optimization for nanotube formation
Barclay, Thomas G.,Constantopoulos, Kristina,Matisons, Janis G.,Zhang, Wei,Fujiki, Michiya
, p. 14172 - 14179,8 (2020/09/02)
Four amphiphiles with l-aspartic acid headgroups (Asp) and a diphenyldiazenyl group (Azo) contained within the hydrophobic tails were designed and synthesized for self-assembly into helically based nanotubes. The amphiphiles of the form R'-{4-[(4-alkylphenyl)diazenyl]phenoxy}alkanoyl-l- aspartic acid (where R' is 10 or 11) varied only in alkyl chain lengths either side of the azo group, having 4, 7, or 10 carbon distal chains and 10 or 11 carbon proximal chains (R-Azo-R'-Asp, where R denotes the number of carbons in the distal chain and R' denotes the number of carbons in the proximal chain). Despite the molecular similarities, distinct differences were identified in the chiral order of the structures self-assembled from hot methanolic aqueous solutions using microscopy and spectroscopic analyses. This was reflected in dominant thermodynamic aggregate morphologies that ranged from amorphous material for 10-Azo-10-Asp, through twisted ribbons (196 ± 49 nm pitch) for 7-Azo-11-Asp, to the desired helically based nanotubes for 4- and 7-Azo-10-Asp (81 ± 11 and 76 ± 6 nm diameters, respectively). Another key variable in the self-assembly of the amphiphiles was the use of a second method to precipitate aggregates from solution at room temperature. This method enabled the isolation of thermodynamically unstable and key transitional structures. Helical ribbons were precursor structures to the nanotubes formed from 4- and 7-Azo-10-Asp as well as the wide, flattened nanotube structures (587 ± 85 nm width) found for 4-Azo-10-Asp. Overall, the results highlighted the interplay of influence of the headgroup and the hydrophobic tail on self-assembly, providing a basis for future rational design of self-assembling amphiphiles.
Synthesis, characterization and thermal and photo alignment behavior of polyethylene imines having butyl substituent azobenzene side chain group
Kamruzzaman, Mohammad,Kuwahara, Yutaka,Ogata, Tomonari,Ujiie, Seiji,Kurihara, Seiji
experimental part, p. 134 - 148 (2012/04/23)
New type of polyethylene imine having butyl (-C4H9) substituent azobenzene side chain group through methylene spacer group (PEI64) was successfully synthesized by solution polycondensation reaction. Synthesized polymer was characteri
