250207-22-8

Basic information

• Product Name: (E,E)-9-tert-butyldiphenylsilyloxy-3,7-dimethyl-2,7-nonadien-4-ol
• Synonyms: (E,E)-9-tert-butyldiphenylsilyloxy-3,7-dimethyl-2,7-nonadien-4-ol
• CAS NO: 250207-22-8
• Molecular Weight: 422.683
• Mol File: 250207-22-8.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: (E,E)-9-tert-butyldiphenylsilyloxy-3,7-dimethyl-2,7-nonadien-4-ol(CAS DataBase Reference)
• NIST Chemistry Reference: (E,E)-9-tert-butyldiphenylsilyloxy-3,7-dimethyl-2,7-nonadien-4-ol(250207-22-8)
• EPA Substance Registry System: (E,E)-9-tert-butyldiphenylsilyloxy-3,7-dimethyl-2,7-nonadien-4-ol(250207-22-8)

Safety Data

• Hazardous Substances Data: 250207-22-8(Hazardous Substances Data)

Upstream product

• 202339-11-5 (E)-tert-butyl{[5-(3,3-dimethyloxiran-2-yl)-3-methylpent-2-en-1-yl]oxy}diphenylsilane 
• 58479-61-1 tert-butylchlorodiphenylsilane 
• 139109-03-8 tert-butyl ({[(2E)-3,7-dimethylocta-2,6-dien-1-yl]oxy})diphenylsilane 
• 106-24-1 Geraniol 
• 3017-71-8 (E)-2-bromobut-2-ene 
• 139109-02-7 (E)-6-((tert-butyldiphenylsilyl)oxy)-4-methylhex-4-enal 

Downstream Products

• 1027184-17-3 (5E,9E)-11-(tert-Butyl-diphenyl-silanyloxy)-4,5,9-trimethyl-2-trimethylsilanyloxy-undeca-5,9-dienenitrile 
• 250207-23-9 (E,E)-10-tert-butyldiphenylsilyloxy-3,4,8-trimethyl-4,8-decadienal 

Relevant articles and documents

Pheromone synthesis, CXCVI. Synthesis of germacrene-B and its extension to the synthesis of (±)-9-methylgermacrene-B, the racemate of the male- produced sex pheromone of the sandfly Lutzomyia longipalpis from Lapinha, Brazil

Both germacrene-B (2) and 9-methylgermacrene-B [(±)-1] were synthesized by employing cyclization reactions [8 → 9 and (±)-20 → (±)-21] as the key steps. The latter [(±)-1] was shown to be the racemate of the male-produced sex pheromone of the sandfly Lutz