250229-64-2

Upstream product

• 40325-99-3 2,6-dimethyl-1,7-heptanediol 
• 101382-88-1 (2S,6R)-7-tert-butyldiphenylsilyloxy-2,6-dimethyl-1-heptanol 
• 75-16-1 methylmagnesium bromide 
• 250229-63-1 (2S,6R)-7-tert-butyldiphenylsilyloxy-2,6-dimethylheptanal 
• 250229-62-0 (2S,6R)-1-acetoxy-7-tert-butyldiphenylsilyloxy-2,6-dimethylheptane 
• 173690-81-8 (2R,6S)-7-acetoxy-2,6-dimethyl-1-heptanol 
• 58479-61-1 tert-butylchlorodiphenylsilane 

Downstream Products

• 270073-65-9 (2R,6S,7R/S)-1-tert-butyldiphenylsilyloxy-2,6-dimethyl-7-tetrahydropyranyloxyoctane 
• 270073-67-1 (2R,6S,7R/S)-2,6-dimethyl-7-tetrahydropyranyloxyoctyl tosylate 
• 250229-65-3 (2S,3S,7R)-8-tert-butyldiphenylsilyloxy-3,7-dimethyl-2-octanol 

Relevant academic research and scientific papers

Synthesis of (3S,7S)- and (3S,7S,15S)- stereoisomers of 3,7-dimethyl-2- heptacosanone and 3,7,15-trimethyl-2-heptacosanone, the ketones identified from the locust Schistocerca gregaria

The (3S,7S) and (3S,7S,15S) stereoisomers of 3,7-dimethyl-2- heptacosanone (1) and 3,7,15-trimethyl-2-heptacosanone (2), the ketones identified from the locust Schistocerca gregaria, were synthesized by employing (2R,6S)-7-acetoxy-2,6-dimethyl-1-heptanol (4) as the starting material.

Pheromone synthesis, CXCVIII. Synthesis of (1S,2S,6S,10R)- and (1S,2R,6R,10R)-1,2,6,10-tetramethyldodecyl propanoate, the components of the sex pheromone of the pine sawfly, Microdiprion pallipes

(1S,2S,6S,10R)- and (1S,2R,6R,10R)-1,2,6,10-tetramethyldodecyl propanoate (1 and 2), the components of the pheromone of Microdiprion pallipes, were synthesized from two chiral and nonracemic building blocks, (R)-3-tert-butoxycarbonyl-2-methylpropanoic acid (D) and (2R,6S)-7-acetoxy- 2,6-dimethyl-1-heptanol (G), by employing lipase-catalyzed kinetic resolution in a later step.