250267-09-5

Basic information

• Product Name: 3-[2-isopropyl-5-methylcyclohexyloxy-(1R,2S,5R)]-2-methyl-2E-propenal
• Synonyms: 3-[2-isopropyl-5-methylcyclohexyloxy-(1R,2S,5R)]-2-methyl-2E-propenal
• CAS NO: 250267-09-5
• Molecular Weight: 224.343
• Mol File: 250267-09-5.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: 3-[2-isopropyl-5-methylcyclohexyloxy-(1R,2S,5R)]-2-methyl-2E-propenal(CAS DataBase Reference)
• NIST Chemistry Reference: 3-[2-isopropyl-5-methylcyclohexyloxy-(1R,2S,5R)]-2-methyl-2E-propenal(250267-09-5)
• EPA Substance Registry System: 3-[2-isopropyl-5-methylcyclohexyloxy-(1R,2S,5R)]-2-methyl-2E-propenal(250267-09-5)

Safety Data

• Hazardous Substances Data: 250267-09-5(Hazardous Substances Data)

Upstream product

• 62055-46-3 3-ethoxy-2-methylacrolein 
• 2216-51-5 (-)-menthol 

Downstream Products

• 250267-11-9 2-methyl-1E,3-butadiene, [2-isopropyl-5-methylcyclohexyl(1R,2S,5R)]ether 

Relevant articles and documents

Photooxygenation of chiral dienol ethers: Asymmetric synthesis of alkoxydioxines

The addition of 1O2 to chiral dienol ethers provides a new route to alkoxydioxines (alkoxyendoperoxides). Depending upon substitution and geometry, the [4+2] cycloaddition is accompanied or even supplanted by [2+2] cycloaddition leading to alkene cleavage and/or ene-like reaction leading to allylic hydroperoxides. The diastereoselectivity of cycloaddition is ultimately limited by the conformational freedom of the dienol ether substrates.