250610-88-9Relevant articles and documents
Synthesis and thermal decomposition studies of some novel dimethyl(phenyl)silyl-substituted aminoboranes
Bowser, James R.,Marohn, Kristina F.,Gilbert, Stephanie R.,Robbins, Andrea M.
, p. 1559 - 1566 (2008/10/09)
Reactions of chloro(dimethyl)phenylsilane with primary amines have been used to obtain a series of compounds having the general formula C6H5(CH3)2SiNHR. The anions of those species are readily prepared, and may be reacted with trichloroborane or dichlorophenylborane to give the corresponding silylaminoboranes, C6H5(CH3)2SiN(R)B(X)Cl (X = Cl, Ph). The thermal properties of these silylaminoboranes have been probed using thermogravimetric analysis. The first step in their thermal degradation involves elimination of C6H5(CH3)2SiCl.