25063-81-4

Basic information

• Product Name: 5-(N-ethyl-N-phenyl)-aminomethylene-2,2-dimethyl-1,3-dioxane-4,6-dione
• CAS NO: 25063-81-4
• Molecular Weight: 275.304
• Mol File: 25063-81-4.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: 5-(N-ethyl-N-phenyl)-aminomethylene-2,2-dimethyl-1,3-dioxane-4,6-dione(CAS DataBase Reference)
• NIST Chemistry Reference: 5-(N-ethyl-N-phenyl)-aminomethylene-2,2-dimethyl-1,3-dioxane-4,6-dione(25063-81-4)
• EPA Substance Registry System: 5-(N-ethyl-N-phenyl)-aminomethylene-2,2-dimethyl-1,3-dioxane-4,6-dione(25063-81-4)

Safety Data

• Hazardous Substances Data: 25063-81-4(Hazardous Substances Data)

Upstream product

• 15568-86-2 5-(ethoxymethylene)-2,2-dimethyl-1,3-dioxane-4,6-dione 
• 103-69-5 N-ethyl-N-phenylamine 

Relevant articles and documents

3-Hydroxypyrroles and 1H-Pyrrol-3(2H)-ones. Part 2. Scope and Limitations of the Synthesis of Pyrrol-3-ones by Pyrolysis of Aminomethylene Meldrum's Acid Derivatives.

Flash vacuum pyrolysis of N,N-disubstituted aminomethylene Meldrum's acid derivatives provides a route to 4,5-unsubstituted 1H-pyrrol-3(2H)-ones by a hydrogen-transfer-cyclisation sequence.Alkyl and aryl 1-substituted, 1,2-disubstituted, and 1,2,2-trisubstituted pyrrolones can be obtained.In competitive cases, there is little selectivity between hydrogen transfer from primary, secondary, or tertiary sites, although benzyl hydrogen atoms proved particularly reactive, giving a general synthesis of 2-phenyl-1H-pyrrol-3(2H)-ones.