25108-45-6Relevant academic research and scientific papers
Regioselective Mono- and Bis-Sulfenylation of Active Methylene Compounds
Devi, Namita,Rahaman, Rajjakfur,Sarma, Kuladip,Barman, Pranjit
supporting information, p. 384 - 388 (2016/02/18)
Selective mono- and bis-sulfenylation of active methylene groups with a variety of disulfides at an ambient temperature is reported. Sulfenylation is promoted by iodine as a catalyst and sulfenyl iodides as intermediates, under metal-free conditions. The
Metal free sulfenylation of active methylene compounds and indole: TBATB mediated synthesis
Rahaman, Rajjakfur,Devi, Namita,Barman, Pranjit
supporting information, p. 4224 - 4227 (2015/06/22)
The present work addresses a development of metal free one pot direct method for sulfenylation of active methylene compounds and indole. The reaction might proceed through sulfenyl bromide as an intermediate, which initiates the C-S bond formation. The re
INVESTIGATION OF THIOSULFONIC ACIDS. XXXIII. REACTION OF ARYL ESTERS OF THIOSULFONIC ACIDS WITH CARBANIONS
Boldyrev, B. G.,Aristarkhova, L. N.,Bilozor, T. K.,Lubenets, V. I.
, p. 1973 - 1975 (2007/10/02)
The reaction of the aryl esters of thiosulfonic acids with substances containing an active methylene group under conditions excluding the formation of arenesulfenic esters (in benzene solution in the presence of triethylamine) leads to the arylthio deriva
INVESTIGATION IN THE REGION OF THIOSULFONIC ACIDS. XXXII. REACTION OF ARYL ESTERS OF THIOSULFONIC ACIDS WITH SUBSTANCES CONTAINING AN ACTIVE METHYLENE GROUP
Boldyrev, B. G.,Aristarkhova, L. N.,Stoyanovskaya, Ya. I.,Bilozor, T. K.
, p. 1160 - 1167 (2007/10/02)
The reactions of the aryl esters of thisulfonic acids with diethyl malonate, ethyl acetoacetate, ethyl cyanoacetate, and acetylacetone in the presence of sodium alcoholates were investigated at various temperatures.Without heat the reaction takes place with the formation of sulfinates and arenesufenic esters, which form their thio derivatives when heated with substances containing an active methylene group in the presence of sodium alcoholates.It was thus demonstrated that under the investigated conditions thioarylating characteristics are exhibited not by the aryl esters of the thiosulfonic acids but by the esters of arenesufenic acids formed as the initial products of these reactions.
