2217-55-2

Basic information

• Product Name: BIS(2,4-DINITROPHENYL) DISULFIDE
• Synonyms: BIS(2,4-DINITROPHENYL) DISULFIDE;2,2',4,4'-TETRANITRODIPHENYL DISULFIDE;bis(2,4-dinitrophenyl)disulfide80+%;Bis(2,4-dinitrophenyl) persulfide;1-(2,4-dinitrophenyl)disulfanyl-2,4-dinitrobenzene;1-(2,4-dinitrophenyl)disulfanyl-2,4-dinitro-benzene
• CAS NO: 2217-55-2
• Molecular Formula: C₁₂H₆N₄O₈S₂
• Molecular Weight: 398.33
• Mol File: 2217-55-2.mol
• Article Data: 20

Chemical Properties

• Melting Point: 280 °C
• Boiling Point: 562.4°Cat760mmHg
• Flash Point: 293.9°C
• Appearance: /
• Density: 1.77g/cm³
• CAS DataBase Reference: BIS(2,4-DINITROPHENYL) DISULFIDE(CAS DataBase Reference)
• NIST Chemistry Reference: BIS(2,4-DINITROPHENYL) DISULFIDE(2217-55-2)
• EPA Substance Registry System: BIS(2,4-DINITROPHENYL) DISULFIDE(2217-55-2)

Safety Data

• Statements: 36/37/38
• Safety Statements: 26-36
• Hazardous Substances Data: 2217-55-2(Hazardous Substances Data)

Usage

General Description

Bis(2,4-dinitrophenyl) disulfide, also known as BDND, is a yellow crystalline compound used as a reagent in organic chemistry. It is commonly utilized in the synthesis of disulfide compounds, as well as in the analysis of thiols and proteins. BDND has the ability to react with thiol groups, forming a colored adduct that is often used for the detection and quantification of thiol-containing molecules. BIS(2,4-DINITROPHENYL) DISULFIDE is also a known sensitizer and can cause skin and eye irritation upon contact, making it important to handle with proper safety precautions.

Upstream product

• 584-48-5 2,4-dinitrobromobenzene 
• 115-08-2 thiocarboxamide 
• 507-09-5 thioacetic acid 
• 1594-56-5 2,4-dinitro-phenyl thiocyanate 
• 76-09-5 2,3-dimethyl-2,3-butane diol 
• 528-76-7 2,4-dinitrobenzenesulfenyl chloride 
• 610-40-2 3,4-dinitro-chlorobenzene 
• 333-20-0 potassium thioacyanate 
• 97-00-7 1-chloro-2,4-dinitro-benzene 
• 140-89-6 potassium ethyl xanthogenate 
• 3898-08-6 1,1-diphenylthiourea 
• 67-64-1 acetone 
• 64-17-5 ethanol 
• 102-08-9 N,N-diphenylthiourea 

Downstream Products

• 82176-61-2 (Z)-4-Dimethylamino-1-(2,4-dinitro-phenylsulfanyl)-3-(3-trifluoromethyl-phenyl)-but-3-en-2-one 
• 17467-91-3 potassium 2,4-dinitrothiophenolate 
• 140455-10-3 2,4-dinitrobenzensulfenic acid potassium salt 
• 61807-32-7 (2,4-dinitro-phenyl)-(2,2-diphenyl-vinyl)-sulfide 
• 35804-37-6 2,4-Dinitrophenyl-benzyl-sulfoxid 
• 835-57-4 methyl 2,4-dinitrophenyl sulfone 
• 31924-73-9 (2,4-dinitro-phenyl)-phenyl-disulfane 
• 24696-61-5 2,4-dinitrophenyl p-tolyl disulfide 
• 969-18-6 1-benzylsulfonyl-2,4-dinitrobenzene 
• 100537-76-6 2-(2,4-dinitro-phenylsulfanyl)-1-phenyl-ethanone 
• 22057-31-4 (2,4-dinitro-phenylsulfanyl)-acetone 
• 35031-15-3 (+/-)-erythro-1-chloro-2-(2.4-dinitro-phenylsulfanyl)-1-(4-methoxy-phenyl)-propane 
• 38434-69-4 (+/-)-threo-3-chloro-(2,4-dinitro-phenylsulfanyl)-butane 
• 5330-96-1 (+/-)-(trans-2-chloro-cyclohexyl)-(2,4-dinitro-phenyl)-sulfide 

Relevant articles and documents

Investigations on 1.3-thiazines, XXXVII: Reactions of NH-acidic tetrahydro-1.3-thiazine derivatives with sulfenic and sulfonic acid chlorides

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A novel dual-nano assisted synthesis of symmetrical disulfides from aryl/alkyl halides

Here, we have reported a novel approach towards dual-nano assisted synthesis of disulfides from coupling of alkyl/aryl halides and sulfur nanoparticles. The indium oxide nanoparticles as catalyst expedite the conversion and sulfur nanoparticle notably enhances the miscibility, providing a faster, high yielding and cost-effective process in ethanol-water system. The method has synthetic advantages in terms of mild reaction framework, catalyst regeneration, and absence of any sulfide or polysulfide linkage as by-product leading to a column free synthesis. A variety of alkyl, aryl and heteroaryl symmetrical disulfides are obtained in good to excellent yields up to exceeding 98%.

An efficient one-pot method for the direct synthesis of organic disulfides from aryl/alkyl halides in the presence of CuCl using morpholin-4-ium morpholine-4-carbo-dithioate

A novel and expedient route is described for the one-pot synthesis of symmetric diaryl (dialkyl) disulfides derivatives via morpholin-4-ium morpholine-4-carbo-dithioate and aryl (alkyl) halides reactions in the presence of CuCl in an aqueous solvent system. Morpholin-4-ium morpholine-4-carbo-dithioate used as new solid, stable and easy handle sulfur Sourcage.