25117-33-3Relevant academic research and scientific papers
Pd/SAPO-41 Bifunctional Catalysts with Enhanced Pd Dispersion Prepared by Ultrasonic-Assisted Impregnation: High Selectivity for n-Hexadecane Hydroisomerization
Bai, Xuefeng,Guo, Chunmu,Jia, Guozhi,Li, Tong,Maximov, A. L.,Su, Xiaofang,Wang, Wei,Wei, Xiaomeng,Wu, Wei
, p. 502 - 511 (2020/05/29)
Two series of Pd/SAPO-41 bifunctional catalysts were synthesized via the ultrasonic-assisted impregnation (xPd/S41-U) with different treating time and conventional incipient wetness impregnation methods (0.30Pd/S41-I) on the SAPO-41 molecular sieve, respe
Cobalt-catalyzed cross-coupling reaction between functionalized primary and secondary alkyl halides and aliphatic Grignard reagents
Cahiez, Gerard,Chaboche, Christophe,Duplais, Christophe,Giulliani, Arianna,Moyeux, Alban
scheme or table, p. 1484 - 1488 (2009/07/01)
The coupling of primary and secondary unactivated alkyl bromides with alkyl-Grignard reagents was performed in good yields under mild conditions by using a new catalytic system: consisting of cobalt chloride and tetramethylethylenediamine (CoCl2·2 LiI, 4TMEDA). The reaction is very chemoselective since ketone, ester and nitrile functions are tolerated.
Radical deoxygenation of tertiary alcohols via trifluoroacetates
Kim, Joong-Gon,Cho, Dae Hyan,Jang, Doo Ok
, p. 3031 - 3033 (2007/10/03)
Trifluoroacetates of tertiary alcohols undergo deoxygenation by Ph 2SiH2 in the presence of (tBuO)2 in excellent yields of the deoxy products without affecting the stereochemistry at β-carbon.
