251346-91-5

Basic information

• Product Name: (3S,5R)-3-Acetoxymethyl-5-methanesulfonyloxymethyl-piperidine-1-carboxylic acid benzyl ester
• Synonyms: (3S,5R)-3-Acetoxymethyl-5-methanesulfonyloxymethyl-piperidine-1-carboxylic acid benzyl ester
• CAS NO: 251346-91-5
• Molecular Weight: 399.465
• Mol File: 251346-91-5.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: (3S,5R)-3-Acetoxymethyl-5-methanesulfonyloxymethyl-piperidine-1-carboxylic acid benzyl ester(CAS DataBase Reference)
• NIST Chemistry Reference: (3S,5R)-3-Acetoxymethyl-5-methanesulfonyloxymethyl-piperidine-1-carboxylic acid benzyl ester(251346-91-5)
• EPA Substance Registry System: (3S,5R)-3-Acetoxymethyl-5-methanesulfonyloxymethyl-piperidine-1-carboxylic acid benzyl ester(251346-91-5)

Safety Data

• Hazardous Substances Data: 251346-91-5(Hazardous Substances Data)

Upstream product

• 124-63-0 methanesulfonyl chloride 
• 206761-38-8 (3S,5R)-3-acetoxymethyl-5-hydroxymethylpiperidine-1-carboxylic acid benzyl ester 

Downstream Products

• 251346-92-6 (3S,5R)-3-Acetoxymethyl-5-azidomethyl-piperidine-1-carboxylic acid benzyl ester 
• 251346-88-0 (1S,2ξ,5S)-2-hydroxy-7-benzyloxycarbonyl-3,7-diazabicyclo[3.3.1]nonane 
• 251346-93-7 (3S,5R)-3-acetoxymethyl-5-aminomethylpiperidine-1-carboxylic acid benzyl ester 
• 251346-95-9 (1S,2ξ,5S)-2-hydroxy-3-t-butyloxycarbonyl-7-benzyloxycarbonyl-3,7-diazabicyclo[3.3.1]nonane 
• 251346-94-8 (3S,5R)-3-hydroxymethyl-5-(t-butyloxycarbonyl)aminomethylpiperidine-1-carboxylic acid benzyl ester 

Relevant articles and documents

An efficient chemoenzymatic access to chiral 3,7- diazabicyclo[3.3.1]nonane derivatives

Enantiopure 3,7-diazabicyclo[3.3.1]nonane derivatives 4 and 5, potential precursors of quinolizidine alkaloids, were synthesised in high yields, starting from the biocatalytic asymmetrization of σ-symmetric 3,5- disubstituted piperidines. Their applicatio