251449-99-7

Upstream product

• 872820-77-4 tris-(4-iodophenyl)methanol 
• 519-73-3 triphenylmethane 

Downstream Products

• 5630-56-8 4,4'-diiodobenzophenone 
• 1020265-99-9 [[4-[[bis(4-iodophenyl)]methyl]phenyl]ethynyl]trimethylsilane 
• 1020266-00-5 [[4-[[(4-iodophenyl)-[4-[[4-[[4-[(triisopropylsilyl)ethynyl]phenyl]ethynyl]phenyl]ethynyl]phenyl]methyl]]phenyl]ethynyl]trimethylsilane 

Relevant academic research and scientific papers

Synthesis of C1- and C 3ν-symmetric porphyrin trimers based on triphenylmethane cores

This work describes the synthesis of a new class of tripodaphyrin derivatives with a triphenylmethane core. Both C 1- and C 3ν-symmetric tetrahedral large molecules with covalently linked rigid elements were obtained.

Improved, Acid-catalyzed Iodinating Procedures for Activated Aromatics with (Diacetoxyiodo)benzene as the Oxidant

Improved procedures for the oxidative, acid-catalyzed iodination of benzene, iodobenzene and several activated aromatics are presented to give mono-, di-, or triiodinated products in 40-82 percent yields. The reactions proceeded at room temperature in the anhydrous systems: arene or hetarene/diiodine/(diacetoxyiodo)benzene (2)/glacial acetic acid/acetic anhydride, acidified with catalytic amounts of concd. (98 percent) H2SO4. Within at most 15 minutes the iodine coloration faded; the following workups are explained. A similar treatment with dibromine gave tribromomesitylene (65 percent), dibromodurene (62 percent), and 2,7-dibromofluoren-9-one (73 percent). A review on the aromatic halogenation reactions with organic trivalent iodine reagents as the oxidants is presented below.