251902-80-4Relevant academic research and scientific papers
Thiocarbonyl ylides and electrophilic azo compounds; sterically hindered cyclic hydrazodicarboxylic esters
Huisgen, Rolf,Li, Xingya,Mloston, Grzegorz,Knorr, Rudolf,Huber, Helmut,Stephenson, David S.
, p. 12783 - 12796 (1999)
The cycloadduct 5, prepared from adamantanethione S-methylide with dimethyl azodicarboxylate, exists in solution in two conformations P and Q (70:30 in CDCl3), which are separated by a barrier of ΔC≠ 18.3 ± 0.6 kcal mol-1; according
