Tetrahedron p. 12783 - 12796 (1999)
Update date:2022-08-05
Topics:
Huisgen, Rolf
Li, Xingya
Mloston, Grzegorz
Knorr, Rudolf
Huber, Helmut
Stephenson, David S.
The cycloadduct 5, prepared from adamantanethione S-methylide with dimethyl azodicarboxylate, exists in solution in two conformations P and Q (70:30 in CDCl3), which are separated by a barrier of ΔC≠ 18.3 ± 0.6 kcal mol-1; according
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