251968-34-0

Basic information

• Product Name: (3S)-methyl-1-tosyloxyheptane
• Synonyms: (3S)-methyl-1-tosyloxyheptane
• CAS NO: 251968-34-0
• Molecular Weight: 284.42
• Mol File: 251968-34-0.mol
• Article Data: 4

Chemical Properties

• CAS DataBase Reference: (3S)-methyl-1-tosyloxyheptane(CAS DataBase Reference)
• NIST Chemistry Reference: (3S)-methyl-1-tosyloxyheptane(251968-34-0)
• EPA Substance Registry System: (3S)-methyl-1-tosyloxyheptane(251968-34-0)

Safety Data

• Hazardous Substances Data: 251968-34-0(Hazardous Substances Data)

Upstream product

• 61169-84-4 (S)-3-methylheptan-1-ol 
• 98-59-9 p-toluenesulfonyl chloride 
• 59614-85-6 (-)-(S)-3-methylheptanoic acid 
• 1753-40-8 (R)-4-menthen-3-one 
• 109622-00-6 methyl (S)-3-methyl-5-oxoheptanoate 
• 677024-82-7 (5R)-1-ethyl-2-isopropyl-5-methylcyclohex-2-enol 
• 677024-84-9 (S)-3-ethyl-2-isopropyl-5-methylcyclohex-2-enone 
• 97424-48-1 (S)-1-bromo-2-methylhexane 
• 131906-75-7 (S)-2-Methylhexyl Tetrahydropyranyl Ether 
• 99833-15-5 (S)-2-methylhexyl 4-methylbenzenesulfonate 
• 84237-05-8 (S)-((3,7-dimethyloct-6-enyloxy)methyl)benzene 
• 7540-51-4 (S)-3,7-dimethyl-6-octen-1-ol 
• 138524-36-4 benzyl ether of 3(S),7-dimethyloctane-1,6-(R,S)-7-triol 
• 138604-47-4 (S)-6-benzyloxy-4-methylhexanal 

Downstream Products

• 99493-42-2 (S)-(+)-14-Methyl-1-octadecene 

Relevant articles and documents

Neutral iridium catalysts with chiral phosphine-carboxy ligands for asymmetric hydrogenation of unsaturated carboxylic acids

We developed neutral iridium catalysts with chiral spiro phosphine-carboxy ligands (SpiroCAP) for asymmetric hydrogenation of unsaturated carboxylic acids. Different from the cationic Crabtree-type catalysts, the iridium catalysts with chiral spiro phosphine-carboxy ligands are neutral and do not require the use of a tetrakis[3,5-bis(trifluoromethyl)phenyl]borate (BArF?) counterion, which is necessary for stabilizing cationic Crabtree-type catalysts. Another advantage of the neutral iridium catalysts is that they have high stability and have a long lifetime in air. The new iridium catalysts with chiral spiro phosphine-carboxy ligands exhibit unprecedented high enantioselectivity (up to 99.4% ee) in the asymmetric hydrogenations of various unsaturated carboxylic acids, particularly for 3-alkyl-3-methylenepropionic acids, which are challenging substrates for other chiral catalysts.

(R)-4-menthenone in the synthesis of optically pure sex pheromone of the peach leafminer moth (Lyonetia clerkella)

The synthesis of (14S)-methyloctadec-1-ene, sex pheromone of the peach leafminer moth (Lyonetia clerkella), is described to demonstrate a new potential of the synthetic use of (R)-4-menthenone.