25209-82-9

Basic information

• Product Name: 2-methylprop-2-en-1-yl phenylcarbamate
• CAS NO: 25209-82-9
• Molecular Formula: C₁₁H₁₃NO₂
• Molecular Weight: 191.2264
• Mol File: 25209-82-9.mol
• Article Data: 1

Chemical Properties

• Boiling Point: 243.1°C at 760 mmHg
• Flash Point: 100.8°C
• Density: 1.103g/cm³
• Vapor Pressure: 0.0328mmHg at 25°C
• Refractive Index: 1.556
• CAS DataBase Reference: 2-methylprop-2-en-1-yl phenylcarbamate(CAS DataBase Reference)
• NIST Chemistry Reference: 2-methylprop-2-en-1-yl phenylcarbamate(25209-82-9)
• EPA Substance Registry System: 2-methylprop-2-en-1-yl phenylcarbamate(25209-82-9)

Safety Data

• Hazardous Substances Data: 25209-82-9(Hazardous Substances Data)

Upstream product

• 103-71-9 phenyl isocyanate 
• 513-42-8 3-hydroxy-2-methyl-1-propene 

Relevant articles and documents

Formation of Ketenimines via the Palladium-Catalyzed Decarboxylative π-Allylic Rearrangement of N-Alloc Ynamides

A new approach for the formation of ketenimines via a decarboxylative allylic rearrangement pathway that does not require strong stabilizing or protecting groups has been developed. The products can be readily hydrolyzed into their corresponding secondary amides or reacted with sulfur ylides to perform an additional [2,3]-Wittig process. Mechanistic studies suggest an outer-sphere process in which reductive alkylation is rate-limiting.