252202-12-3Relevant articles and documents
Atropo-enantioselective synthesis of an axially chiral C1-symmetric phosphine ligand and its application in the asymmetric hydrosilylation of styrenes
Bringmann, Gerhard,Wuzik, Andreas,Breuning, Matthias,Henschel, Petra,Peters, Karl,Peters, Eva-Maria
, p. 3025 - 3031 (2007/10/03)
The axially chiral monodentate phosphine P-8 was synthesized in enantiomerically pure form, starting from the readily available, configurationally unstable lactone 1. Furthermore, its application as a ligand in the Pd-catalyzed stereoselective hydrosilyla