25221-74-3Relevant academic research and scientific papers
Photoinduced electron-transfer cope rearrangements of 3,6-diaryl-2,6- octadienes and 2,5-diaryl-3,4-dimethyl-1,5-hexadienes: Stereospecificity and an unexpected formation of the bicyclo[2.2.0]hexane Derivatives
Ikeda, Hiroshi,Takasaki, Toshihiko,Takahashi, Yasutake,Konno, Akinori,Matsumoto, Masao,Hoshi, Yosuke,Aoki, Takashi,Suzuki, Takanori,Goodman, Joshua L.,Miyashi, Tsutomu
, p. 1640 - 1649 (2007/10/03)
Under the 9,10-dicyanoanthracene-sensitized photoinduced electron- transfer conditions, (Z,Z)-, (E,E)-, (E,Z)-3,6-diaryl-2,6-octadiene and (d,l),(meso)-2,5-diaryl-3,4-dimethyl-1,5-hexadiene stereospecifically undergo the Cope rearrangement to give a Cope
