252256-92-1Relevant academic research and scientific papers
Hexahomotrioxacalix[3]arene: A scaffold for a C3-symmetric phosphine ligand that traps a hydrido-rhodium fragment inside a molecular funnel
Dieleman, Cedric B.,Matt, Dominique,Neda, Ion,Schmutzler, Reinhard,Harriman, Anthony,Yaftian, Reza
, p. 1911 - 1912 (1999)
Stereoselectivity around an H-Rh-CO fragment has been realized by reaction of the hexahomotrioxacalix[3]arene-derived triphosphine 4 with [Rh(acac)(CO)2]; the resultant trigonal bipyramidal complex has the Rh-H bond directed inside the cavity.
