25236-74-2Relevant academic research and scientific papers
PALLADIUM-CATALYZED ADDITION REACTION OF OLEFINS, CARBON TETRACHLORIDE AND CARBON MONOXIDE IN ALCOHOLS TO GIVE 2-ALKYL-4,4,4-TRICHLOROBUTANOATES
Tsuji, Jiro,Sato, Koji,Nagashima, Hideo
, p. 5003 - 5006 (2007/10/02)
Pd(OAc)2 combined with PPh3 is good catalyst for the addition reaction of CCl4 and CO to olefins in ethanol to afford ethyl 2-alkyl-4,4,4-trichlorobutanoates.The esters were obtained in satisfactory yields when the reaction was carried out at 50 deg C in
