252565-06-3Relevant academic research and scientific papers
Bis(cyclohexane-1,3-dionato)-C2,O 1-(ethylenediamine-N,N′)platinum(II) trihydrate and bis(cyclohexane-1,3-dionato)-C2,O 1-(N,N-dimethylethylenediamine-N,N′)-platinum(II)
Yuge, Hidetaka,Miyamoto, Takeshi Ken
, p. 1617 - 1620 (1999)
In each of the title organoplatinum(II) compounds, [Pt(C6H7O2)2(C2H 8N2)]·3H2O, (1), and [Pt(C6H7O2)2-(C4H 12N2)], (2), one 1,3-cyclohexanedionate monoanion is bound to the Pt atom at the Csp3 atom and the other is bound at the enolate O atom. The Pt - C bond lengths in (1) and (2) are 2.123 (4) and 2.108 (5) A, respectively. The shorter Pt - C distance in (2) may be due to a trans influence of the NMe2 moiety of the N,N-dimethylethylenediamine ligand.
