Bis(cyclohexane-1,3-dionato)-C2,O 1-(ethylenediamine-N,N′)platinum(II) trihydrate and bis(cyclohexane-1,3-dionato)-C2,O 1-(N,N-dimethylethylenediamine-N,N′)-platinum(II)

DOI: 10.1107/S0108270199008069

Source and publish data:

Acta Crystallographica, Section C: Crystal Structure Communications p. 1617 - 1620 (1999)

Update date:2022-08-05

Topics:

Authors:

Yuge, Hidetaka

Miyamoto, Takeshi Ken

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Article abstract of DOI:10.1107/S0108270199008069

In each of the title organoplatinum(II) compounds, [Pt(C₆H₇O₂)₂(C₂H ₈N₂)]·3H₂O, (1), and [Pt(C₆H₇O₂)₂-(C₄H ₁₂N₂)], (2), one 1,3-cyclohexanedionate monoanion is bound to the Pt atom at the Csp³ atom and the other is bound at the enolate O atom. The Pt - C bond lengths in (1) and (2) are 2.123 (4) and 2.108 (5) A, respectively. The shorter Pt - C distance in (2) may be due to a trans influence of the NMe₂ moiety of the N,N-dimethylethylenediamine ligand.

Full text of DOI:10.1107/S0108270199008069

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