252667-35-9Relevant articles and documents
Pd(O)-catalyzed reaction of alkynes with trifurylgermane and CO providing acylgermanes: The example of hydrometalcarbonylation of alkynes
Kinoshita, Hidenori,Shinokubo, Hiroshi,Oshima, Koichiro
, p. 4220 - 4221 (2002)
A direct synthesis of acylmetals from alkynes with group 14 metal hydride and CO is reported. The Pd(0)-catalyzed reaction of alkynes with tri(2-furyl)germane under ambient pressure of CO provides α,β-unsaturated acylgermanes in good yields. Conversion of acylgermanes to the corresponding amides is achieved. Copyright