25287-24-5

Upstream product

• 104-94-9 4-methoxy-aniline 
• 766-97-2 4-n-methylphenylacetylene 
• 122-00-9 para-methylacetophenone 

Downstream Products

• 1439402-22-8 C₂₆H₃₂ClIrNO 
• 1601494-48-7 2-(4-methoxyphenyl)-6-methyl-1-methylene-3,4-diphenyl-1,2-dihydroisoquinoline 
• 1601494-57-8 2,3,4-tris(4-methoxyphenyl)-6-methyl-1-methylene-1,2-dihydroisoquinoline 
• 1601494-59-0 2-(4-methoxyphenyl)-6-methyl-1-methylene-3,4-di-p-tolyl-1,2-dihydroisoquinoline 
• 1601494-61-4 3,4-bis(3-chlorophenyl)-2-(4-methoxyphenyl)-6-methyl-1-methylene-1,2-dihydroisoquinoline 
• 1601494-63-6 3,4-bis(4-fluorophenyl)-2-(4-methoxyphenyl)-6-methyl-1-methylene-1,2-dihydroisoquinoline 
• 1601494-65-8 2-(4-methoxyphenyl)-6-methyl-1-methylene-3,4-di-n-propyl-1,2-dihydroisoquinoline 
• 1601495-01-5 C₂₄H₂₈⁽²⁾HNO 
• 1601494-80-7 2-(4-methoxyphenyl)-1,6-dimethyl-3,4-di-n-propyl-1,2-dihydroisoquinoline 
• 1601494-67-0 2-(4-methoxyphenyl)-4,6-dimethyl-1-methylene-3-phenyl-1,2-dihydroisoquinoline 
• 1601494-78-3 2-(4-methoxyphenyl)-1,4,6-trimethyl-3-phenyl-1,2-dihydroisoquinoline 
• 1601494-69-2 4-ethyl-2-(4-methoxyphenyl)-6-methyl-1-methylene-3-phenyl-1,2-dihydroisoquinoline 
• 1601494-71-6 4-n-butyl-2,3-bis(4-methoxyphenyl)-6-methyl-1-methylene-1,2-dihydroisoquinoline 
• 1601494-72-7 4-n-butyl-3-(4-fluorophenyl)-2-(4-methoxyphenyl)-6-methyl-1-methylene-1,2-dihydroisoquinoline 

Relevant academic research and scientific papers

Oxidative Kinetic Resolution of Acyclic Amines Based on Equilibrium Control

An oxidative kinetic resolution of racemic acyclic amines was developed using an imine derivative as the resolving reagent and chiral phosphoric acid as the catalyst to give enantiomers in good yields with high to excellent enantioselectivities. The key t

A Rhodium-Catalyzed [3 + 2] Annulation of General Aromatic Aldimines/Ketimines and N-Substituted Maleimides

A new class of rhodium-catalyzed, C-H activation triggered [3 + 2] annulations of aromatic aldimines or ketimines and maleimides was reported in this study. A broad scope of general imines without electron-withdrawing groups were successfully activated an

A Rhodium-Catalyzed [3 + 2] Annulation of General Aromatic Aldimines/Ketimines and N-Substituted Maleimides

A new class of rhodium-catalyzed, C-H activation triggered [3 + 2] annulations of aromatic aldimines or ketimines and maleimides was reported in this study. A broad scope of general imines without electron-withdrawing groups were successfully activated an

Decrypting Transition States by Light: Photoisomerization as a Mechanistic Tool in Br?nsted Acid Catalysis

Despite the wide applicability of enantioselective Br?nsted acid catalysis, experimental insight into transition states is very rare, and most of the mechanistic knowledge is gained by theoretical calculations. Here, we present an alternative approach (de

Room temperature hydroamination of alkynes with anilines catalyzed by anti-Bredt di(amino)carbene gold(i) complexes

The room temperature hydroamination of alkynes with phenylhydrazine and anilines was achieved with an anti-Bredt di(amino) carbene gold(i) chloride as precatalyst, in the presence of KBArF as chloride scavenger. These reactions were highly regioselective and excellent conversions were obtained (up to 99%) for a series of alkynes and anilines.

Comparison of the 13C (C=N) chemical shifts of substituted N-(phenyl-ethylene)-anilines and substituted N-(benzylidene)-anilines

Comparison of 13C NMR of C=N bond chemical shifts δC(C=N) in substituted N-(phenyl-ethylene)-anilines XArC(Me)=NArY (XPEAYs) with that in substituted N-(benzylidene)-anilines XArCH=NArY (XBAYs) was carried out. The δC(C=N)

Highly enantioselective imine hydrogenation catalyzed by ruthenium phosphane-phosphite diamine complexes

Mildly does it: A highly enantioselective catalyst for the hydrogenation of N-aryl imines is described (see scheme). This catalyst offers practical advantages because it operates under very mild conditions and is based on an Ru complex with a diamine as t

Rhodium(III)-catalyzed hydroamination of aromatic terminal alkynes with anilines

The dinuclear Rh(III) species [Cp*RhCl2]2 catalyzes the hydroamination reaction between an aromatic terminal alkyne (ArCCH) and an aniline (Ar′NH2), in the presence of a salt additive, to afford the ketimine Ar′N=C(Me)(Ar). A reaction pathway has been proposed on the basis of experimental and computational studies.

The potassium hydride mediated trimerization of imines

A novel reaction, the potassium hydride mediated synthesis of fulvenes, is described. The synthesis utilizes N-aryl imines as an inexpensive starting material affording novel substituted aminofulvenes. It is proposed that the presence of the metalated enamine as well as the imine (ratio 21) leads to the formation of an initial dimerization and a transient trimerization product, which cyclizes, giving rise to the aminofulvene.

Novel amido-complexes for the efficient asymmetric hydrogenation of imines

Novel N,N,P ligand stabilized rhodium complexes exhibiting high activities and enantioselectivities in the asymmetric hydrogenation of N-aryl imines are introduced. The ligands were synthesized from inexpensive starting materials and their modular design