25315-69-9Relevant academic research and scientific papers
Design and synthesis of 2-(1,3-dialkoxy-2-methylpropan-2-yl)-1,3- diarylpropanes as tethering units for folded H-stacking polymers
Moriai, Ryota,Naito, Yu-Suke,Nomura, Ryosuke,Funyu, Shigeaki,Ishitsuka, Ken-Ich,Asano, Naoki,Okamoto, Sentaro
, p. 2649 - 2653 (2014/05/06)
1,3-Diarylpropenes 9 having a 1,3-dialkoxy-2-methylpropan-2-yl group were designed as tethering monomers for folded H-stacking polymers, and were readily synthesized from 2-ethoxymethylidene malonate in four- or five-steps, including a facile sequential a
Effect of deuterium on the kinetics of 1,5-hydrogen shifts: 5-Dideuteriomethylene-2,4,6,7,9-pentamethyl-11,11a-dihydro-12H-naphthacene
Von Doering, William E.,Keliher, Edmund J.
, p. 2488 - 2495 (2007/10/03)
To obtain a more reliable temperature dependence of the kinetic deuterium isotope effect in a 1,5-hydrogen shift, the title compound has been designed to repress compromising side reactions, arguably arising from second-order ene-ene unions. The values of
A facile one-step synthesis of ethyl 2-(1,1-dialkyl and arylmethyl) malonates
Kim, Young Mee,Kwon, Tae Woo,Chung, Sung Kee,Smith, Michael B.
, p. 343 - 350 (2007/10/03)
Diethyl ethoxymethylenemalonate (EMME) is unexpectedly converted into diethyl 2-(1,1-dialkyl and diarylmethyl) malonate derivatives by a classical Grignard reaction. Addition of organocuprates to EMME gave diethyl 2-(1- ethoxyalkyl) malonate derivatives.
