253159-03-4Relevant articles and documents
Synthesis and Atropo-diastereoselective Ring Cleavage of a [Cp*Ru]-Complexed Biaryl Lactone: Experimental and Computational Investigations
Bringmann, Gerhard,Wuzik, Andreas,Stowasser, Ralf,Rummey, Christian,G?bel, Lothar,Stalke, Dietmar,Pfeiffer, Matthias,Schenk, Wolfdieter A.
, p. 5017 - 5021 (1999)
The planar-chiral biaryl lactone complex 5b is cleaved highly atropo-diastereoselectively by simple O-nucleophiles. Toward H-nucleophiles, it shows a different reactivity behavior consistent with DF calculations using the Fukui function.