253160-96-2Relevant academic research and scientific papers
β-Phosphatoxyalkyl Radical Reactions: Competing Phosphate Migration and Phosphoric Acid Elimination from a Radical Cation - Phosphate Anion Pair Formed by Heterolytic Fragmentation
Newcomb, Martin,Horner, John H.,Whitted, Patrick O.,Crich, David,Huang, Xianhai,Yao, Qingwei,Zipse, Hendrik
, p. 10685 - 10694 (2007/10/03)
β-Phosphatoxyalkyl radical reactions were studied experimentally and computationally. The 1,1-dibenzl-2-(diphenylphosphatoxy)-2-phenylethyl radical (1) reacted to give the migration product 2-benzyl-2-(diphenylphosphatoxy)-1,3-diphenylpropyl radical (2) a
