253160-97-3

Upstream product

• 3696-28-4 2,2'-dipyridyl disulfide bis-N-oxide 
• 253161-05-6 3-(diphenoxy-phosphoryloxy)-3-methyl-2-phenyl-butyric acid 
• 2524-64-3 chlorophosphoric acid diphenyl ester 
• 253161-04-5 3-(diphenoxy-phosphoryloxy)-3-methyl-2-phenyl-butyric acid 2,4-dimethoxy-benzyl ester 
• 258876-09-4 2,4-dimethoxybenzyl phenylacetate 

Relevant academic research and scientific papers

Inter- and intramolecular pathways for the formation of tetrahydrofurans from β-(phosphatoxy)alkyl radicals. Evidence for a dissociative mechanism

β-(Phosphatoxy)alkyl radicals generated by photolysis of Barton PTOC esters in the presence of allyl alcohol and tert-butyl mercaptan undergo nucleophilic substitution followed by 5-exo-trig radical ring closure leading to tetrahydrofurans in good yield and with high trans selectivity. β- (Phosphatoxy)alkyl radicals obtained by intramolecular hydrogen 1,5- abstraction with an alkoxyl radical undergo nucleophilic displacement providing tetrahydrofurans. The ensemble of results, including the effects of leaving groups and substituents, strongly support a dissociative mechanism for these radical nucleophilic displacement reactions.

β-Phosphatoxyalkyl Radical Reactions: Competing Phosphate Migration and Phosphoric Acid Elimination from a Radical Cation - Phosphate Anion Pair Formed by Heterolytic Fragmentation

β-Phosphatoxyalkyl radical reactions were studied experimentally and computationally. The 1,1-dibenzl-2-(diphenylphosphatoxy)-2-phenylethyl radical (1) reacted to give the migration product 2-benzyl-2-(diphenylphosphatoxy)-1,3-diphenylpropyl radical (2) a