253189-24-1

Upstream product

• 994-30-9 triethylsilyl chloride 
• 253189-23-0 C₅₁H₇₄ClIN₂O₁₂Si₂ 
• 253189-14-9 (4S,5R)-2-Iodo-4,5-bis-methoxymethoxy-cyclopent-2-enone 
• 253189-21-8 (R)-3-tert-Butoxycarbonylamino-3-{5-[(5R,6R,7S)-6-(tert-butyl-dimethyl-silanyloxy)-9-iodo-2,2-dimethyl-1,3-dioxa-spiro[4.4]non-8-en-7-yloxy]-6-chloro-pyridin-2-yl}-propionic acid 
• 253189-35-4 (R)-3-tert-Butoxycarbonylamino-3-{5-[(5R,6R,7S)-6-(tert-butyl-dimethyl-silanyloxy)-9-iodo-2,2-dimethyl-1,3-dioxa-spiro[4.4]non-8-en-7-yloxy]-6-chloro-pyridin-2-yl}-propionic acid methyl ester 
• 253189-34-3 (R)-3-tert-Butoxycarbonylamino-3-{5-[(1S,4R,5R)-5-(tert-butyl-dimethyl-silanyloxy)-4-hydroxy-4-hydroxymethyl-3-iodo-cyclopent-2-enyloxy]-6-chloro-pyridin-2-yl}-propionic acid methyl ester 
• 253189-30-9 Acetic acid (1R,2R,5S)-2-acetoxymethyl-5-(tert-butyl-dimethyl-silanyloxy)-2-hydroxy-3-iodo-cyclopent-3-enyl ester 
• 253189-28-5 Acetic acid (1R,4S,5R)-1-acetoxymethyl-2-iodo-4,5-bis-methoxymethoxy-cyclopent-2-enyl ester 
• 253189-17-2 Acetic acid (1R,2R,5S)-2-acetoxymethyl-2,5-dihydroxy-3-iodo-cyclopent-3-enyl ester 
• 253189-16-1 (1R,4S,5R)-1-Hydroxymethyl-2-iodo-4,5-bis-methoxymethoxy-cyclopent-2-enol 
• 253189-15-0 (3S,6S,7R)-4-Iodo-6,7-bis-methoxymethoxy-1-oxa-spiro[2.4]hept-4-ene 

Downstream Products

• 253189-26-3 C₅₇H₈₇ClN₂O₁₂Si₃ 

Relevant academic research and scientific papers

Synthesis of the entire carbon framework of the kedarcidin chromophore aglycon

In advanced studies directed toward the total synthesis of the kedarcidin chromophore, we have successfully achieved the late-stage installation of the nine-membered diyne ring in the presence of the highly functionalised ansamacrocyclic bridge. The Royal

Synthetic study of kedarcidin chromophore: Atropselective construction of the ansamacrolide

The ansamacrolide moiety of kedarcidin has been constructed with complete atropselectivity via intramolecular Sonogashira coupling.