253670-66-5

Basic information

• Product Name: (E)-2-ethoxy-1,1,1-trifluoro-6,6-dimethyl-3-(phenylthio)hept-2-en-4-yne
• Synonyms: (E)-2-ethoxy-1,1,1-trifluoro-6,6-dimethyl-3-(phenylthio)hept-2-en-4-yne
• CAS NO: 253670-66-5
• Molecular Weight: 328.398
• Mol File: 253670-66-5.mol

Chemical Properties

• CAS DataBase Reference: (E)-2-ethoxy-1,1,1-trifluoro-6,6-dimethyl-3-(phenylthio)hept-2-en-4-yne(CAS DataBase Reference)
• NIST Chemistry Reference: (E)-2-ethoxy-1,1,1-trifluoro-6,6-dimethyl-3-(phenylthio)hept-2-en-4-yne(253670-66-5)
• EPA Substance Registry System: (E)-2-ethoxy-1,1,1-trifluoro-6,6-dimethyl-3-(phenylthio)hept-2-en-4-yne(253670-66-5)

Safety Data

• Hazardous Substances Data: 253670-66-5(Hazardous Substances Data)

Upstream product

• 917-92-0 3,3-Dimethylbut-1-yne 
• 236121-24-7 (E)-2-ethoxy-1,1,1-trifluoro-3-(phenylthio)prop-2-ene 

Downstream Products

• 253670-75-6 (E)-2-ethoxy-1,1,1-trifluoro-6,6-dimethyl-3-(phenylsulfonyl)hept-2-en-4-yne 

Relevant articles and documents

Palladium-catalyzed terminal alkyne coupling reaction of β-bromo-β- phenylthio or β-methylthio-α-trifluoromethyl enol ethers: A convenient synthesis of 2-sulfonyl-1-buten-3-ynes

2-Sulfonyl-1-buten-3-yne (2-sulfonyl enyne) 7 was obtained via the Pd- catalyzed cross-coupling reactions of β-bromo enol ethers 3 and 4 and successive oxidation with m-chloroperbenzoic acid.