25409-22-7Relevant academic research and scientific papers
A short synthesis of naturally occurring and other analogues of plakinic acids that contain the 1,2-dioxolane group
Bloodworth,Bothwell, Brian D.,Collins, Andrew N.,Maidwell, Nicola L.
, p. 1885 - 1888 (1996)
Natural and unnatural analogues 4 of plakinic acids A, C and D have been prepared in three steps from alkan-2-ones by (i) LDA-induced condensation with ethyl-3-methylbut-2-enoate to give (2Z)-3,5-dimethylalka-2,4-dienoic acids 10, then (ii) isomerisation to the 2E-isomers 5 and finally (iii) peroxymercuriation with 30% hydrogen peroxide and reduction in situ with sodium borohydride.
REFORMATSKY REACTION USING Zn/Ag COUPLE
Bortolussi, Michel,Seyden-Penne, Jacqueline
, p. 2355 - 2362 (2007/10/02)
The Reformatsky reaction is easy to run in ethereal solvents in the presence of Zn/Ag couple.From methyl γ-bromocrotonate and krtones, remified esters are fromed in refluxing Et2O, linear ones in refluxing THF.
