25424-26-4Relevant academic research and scientific papers
These screws Diazafluorene derivetive and manufacturing method
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Paragraph 0026; 0031, (2016/12/22)
PROBLEM TO BE SOLVED: To provide an organic photoconductor for obtaining an electrophotographic photoreceptor having high responsiveness and high durability to repetitive use, to provide a compound especially useful as an electron transport material and to provide a method for producing the compound. SOLUTION: There is provided a bisdiazapentadiene derivative represented by chemical formula (1). (In formula, R represents a hydrogen atom or a tert-butyl group; and Ar represents a p-phenylene group or a m-phenylene group). COPYRIGHT: (C)2013,JPOandINPIT
The albatrossenes: Large, cleft-containing, polyphenyl polycyclic aromatic hydrocarbons
Tong, Ling,Ho, Douglas M.,Vogelaar, Nancy J.,Schutt, Clarence E.,Pascal Jr., Robert A.
, p. 7291 - 7302 (2007/10/03)
The syntheses and X-ray structures of very large polycyclic aromatic compounds containing clefts defined by polyphenylaryl groups are described. The C2-symmetric 'albatrossenes' 1,3-bis(heptaphenyl-2-naphthyl)benzene (7a) and 1,3-bis(heptaphenyl-1-naphthyl)benzene (12a), as well as brominated derivatives, were synthesized by the addition of tetraphenylbenzyne to the appropriate polyphenyl biscyclopentadienones. The 2-naphthyl isomers have wide, shallow clefts, and the 1-naphthyl isomers have deep, narrow clefts which were observed to change size dramatically in different crystal environments. In a similar way, 1,3,5-tris(pentaphenylphenyl)benzene (19), a D3-symmetric molecular propeller with a diameter of 21 ?, and 1,3,5-tris(heptaphenyl-2-naphthyl)benzene (22) were prepared by the addition of diphenylacetylene and tetraphenylbenzyne, respectively, to a triscyclopentadienone.
Process for synthesizing bis (phenylglyoxyloyl)benzenes usable for manufacturing polyphenylquinoxaline resins
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, (2008/06/13)
Bis (phenylglyoxyloyl) benzenes are manufactured by a method comprising the reaction of terephthalic or isophthalic aldehyde first with a low proportion of an alkali metal cyanide in a solvent, and then with benzaldehyde; the resultant product is oxidized to the desired bis (phenylglyoxyloyl) benzene.
