25438-40-8Relevant academic research and scientific papers
Metal free mild and selective aldehyde cyanosilylation by a neutral penta-coordinate silicon compound
Swamy,Bisai, Milan Kumar,Das, Tamal,Sen, Sakya S.
, p. 6910 - 6913 (2017)
This study demonstrates the preparation and structural characterization of a Si(iv) hydride (PhC(NtBu)2SiH(CH3)Cl) (1) and its use as a catalyst for the cyanosilylation of a variety of aldehydes. Compound 1 represents the first neutr
Beyond Hydrofunctionalisation: A Well-Defined Calcium Compound Catalysed Mild and Efficient Carbonyl Cyanosilylation
Yadav, Sandeep,Dixit, Ruchi,Vanka, Kumar,Sen, Sakya S.
supporting information, p. 1269 - 1273 (2018/02/06)
Organocalcium compounds have been reported as efficient catalysts for various transformations, for cases in which one of the substrates contained an E?H (E=B, N, Si, P) bond. Here, we look at the possibility of employing an organocalcium compound for a tr
Efficient and selective aldehyde cyanosilylation catalyzed by Mg-Li bimetallic complex
Li, Jia,Yu, Ting,Luo, Man,Xiao, Qian,Yao, Weiwei,Xu, Li,Ma, Mengtao
, p. 83 - 86 (2018/09/06)
A NCN-pincer ligand-based Mg-Li bimetallic complex [NCN-MgBr2][Li(THF)4] 1 has been employed as an efficient catalyst for cyanosilylation of a wide range of aldehydes with trimethylsilyl cyanide (TMSCN) at room temperature in CDClsu
