25462-68-4Relevant academic research and scientific papers
Benzodipyrrole-based Donor–Acceptor-type Boron Complexes as Tunable Near-infrared-Absorbing Materials
Nakamura, Tomoya,Furukawa, Shunsuke,Nakamura, Eiichi
supporting information, p. 2016 - 2020 (2016/07/28)
Benzodipyrrole-based donor–acceptor boron complexes were designed and synthesized as near-infrared-absorbing materials. The electron-rich organic framework combined with the Lewis acidic boron co-ordination enabled us to tune the LUMO energy level and the HOMO–LUMO gap (i.e.,the absorption wavelength) by changing the organic acceptor units, the number of boron atoms, and the substituents on the boron atoms.
Synthesis of bromine- or aryl-substituted ditopic Schiff base ligands and their bimetallic iron(II) complexes: Electronic and magnetic properties
Wilson, Danielle,Djukic, Brandon,Lemaire, Martin T.
, p. 17 - 24 (2014/03/21)
Syntheses of three new ditopic Schiff base ligands bearing bromine, phenyl or 2-thienyl substituents are described. Bimetallic iron(II) complexes were prepared from these ligands and were characterized. Electrochemical measurements suggest no measurable electronic coupling between the metal ions in each complex. Variable temperature magnetic susceptibility measurements indicate gradual spin-crossover is operative in the complexes studied, with the low-spin state as the ground state in all cases. Density functional theory calculations corroborate these experimental observations. Attempts to electropolymerize the 2-thienyl-substituted complexes were not successful.
Synthesis of terphenyl oligomers as molecular electronic device candidates
Maya, Francisco,Tour, James M.
, p. 81 - 92 (2007/10/03)
Six functionalized bis(phenylene ethynylene)-p,p-terphenyls (BPETs) have been synthesized as potential molecular electronic devices. The molecules containing mono- and dinitro terphenyl cores, were rationally designed based on the electronic properties recently found in oligo(phenylene ethynylene)s (OPEs). From our understanding of the conductance properties in OPEs, improvement of electronic properties may be possible by using BPETs due to a higher rotational barrier between the central aromatic rings of the compounds prepared here. BPETs cores were functionalized with nitro groups and with different metallic adhesion moieties (alligator clips) to provide new compounds for testing in the nanopore and planar testbed structures.
An improved synthesis and structural characterisation of 2-(4-acetylthiophenylethynyl)-4-nitro-5-phenylethynylaniline: The molecule showing high negative differential resistance (NDR)
Wang, Changsheng,Batsanov, Andrei S.,Bryce, Martin R.,Sage, Ian
, p. 2089 - 2095 (2007/10/03)
2-(4-Acetylthiophenylethynyl)-4-nitro-5-phenyl-ethynylaniline (11) has been synthesised by an improved route, which has many advantages over the literature procedure. A key intermediate is 2-ethynyl-4-nitro-5-phenylethynylaniline (6) which is obtained fro
Phenylene ethynylene diazonium salts as potential self-assembling molecular devices
Kosynkin, Dmitry V.,Tour, James M.
, p. 993 - 995 (2007/10/03)
(matrix presented) Functionalized diazonium salts for molecular electronic devices are prepared by the reaction of the corresponding anilines with NOBF4 in sulfolane-acetonitrile solvent.
Dyeing compositions for keratinic fibres, based on halogenated meta-phenylenediamines
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, (2008/06/13)
The invention relates to dyeing compositions for direct dyeing of keratinic fibres, containing, in a cosmetically acceptable medium: (a) at least one yellow or green-yellow dye corresponding to the formula (I): STR1 in which X=Cl, Br, F, and R1
