2547-26-4Relevant academic research and scientific papers
Preparation and Assignment of Configuration of cis- and trans-2,3,4,4a,5,6-Hexahydro-2-naphthalenol
Underiner, Ted L.,Goering, Harlan L.
, p. 897 - 900 (1987)
The two diastereomers of 2,3,4,4a,5,6-hexahydro-2-naphthalenol (cis-1-OH and trans-1-OH) have been prepared and configurations have been established by correlation with the diastereomeric 9-methyldecalins (8).The correlations also establish configurations of the diastereomeric 3,4,4a,5,6,8a-hexahydro-8a-methylnaphthalenes (2).Configurations have also been established for the isomeric 2,3,4,4a,5,6-hexahydro-2-methylnaphthalenes (3) by correlation with the corresponding 2-methyldecalins.
Ring closure of the 6-methylenecyclodecyl radical
Beckwith,Bowry,Schiesser
, p. 121 - 130 (2007/10/02)
Treatment of the dithiocarbonate, 10a, derived from 6-methylenecyclodecanol, with tributylstannane affords a mixture of the cis- and trans-isomers of 9-methyldecahydronaphthalene, in which the former predominates, but no methylenecyclodecane. The reaction
New Stereoselective Synthesis of 9-Methyl-cis-decalin Derivatives by Double Michael Reaction of 3-Methyl-4-methylenecyclohex-2-enone and its Congeners with Dimethyl 3-Oxoglutarate
Irie, Hiroshi,Mizuno, Yukio,Taga, Tooru,Osaki, Kenji
, p. 25 - 30 (2007/10/02)
Double Michael reaction of 3-methyl-, 2,3-dimethyl-, and 3,5-dimethyl-4-methylenecyclohex-2-enone with dimethyl 3-oxoglutarate in dimethyl sulphoxide in the presence of potassium fluoride gave stereoselectively 9-methyl-, 1,9-dimethyl-, and 4,9-dimethyl-6
Efficient Coupling of Tertiary Alkyl Halides with Dialkylzinc and Titanium Compounds
Reetz, Manfred T.,Wenderoth, Bernd,Peter, Roland,Steinbach, Rainer,Westermann, Juergen
, p. 1202 - 1204 (2007/10/02)
Dialkylzinc compounds react with tertiary halides to afford the corresponding coupling products containing a quaternary carbon atom, thereby making geminal dialkylation of ketones or hydroalkylation of olefins possible.
