2547-27-5Relevant academic research and scientific papers
Ring closure of the 6-methylenecyclodecyl radical
Beckwith,Bowry,Schiesser
, p. 121 - 130 (2007/10/02)
Treatment of the dithiocarbonate, 10a, derived from 6-methylenecyclodecanol, with tributylstannane affords a mixture of the cis- and trans-isomers of 9-methyldecahydronaphthalene, in which the former predominates, but no methylenecyclodecane. The reaction
Efficient Coupling of Tertiary Alkyl Halides with Dialkylzinc and Titanium Compounds
Reetz, Manfred T.,Wenderoth, Bernd,Peter, Roland,Steinbach, Rainer,Westermann, Juergen
, p. 1202 - 1204 (2007/10/02)
Dialkylzinc compounds react with tertiary halides to afford the corresponding coupling products containing a quaternary carbon atom, thereby making geminal dialkylation of ketones or hydroalkylation of olefins possible.
