50638-66-9Relevant academic research and scientific papers
On the ethenolysis of natural rubber and squalene
Wolf, Stefanie,Plenio, Herbert
, p. 2008 - 2012 (2011)
We report here the ethenolysis of squalene and natural rubber utilizing (NHC)(NHCewg)RuCl2(= CRR') and Grubbs-Hoveyda complexes. 0.01 mol% [Ru] per double bond are sufficient for extensive squalene cleavage, resulting in the formation of numerous terminal olefins, which were identified by GC/MS. The depolymerization of natural rubber requires 0.1 mol% [Ru] and leads to the formation of various oligomeric isoprenes, several of which (n = 2-6) were isolated and characterized.
