254734-22-0Relevant articles and documents
Reactions of β-aminoenones with acetylhydrazine, semicarbazide and methoxycarbonylhydrazine. Synthesis of 1-acetyl-, 1-carboxamide- or methyl 1- carboxylated pyrazole derivatives
Alberola, Angel,Calvo, Luis,Ortega, Alfonso Gonzalez,Sadaba, M. Luisa,Sanudo, M. Carmen,Granda, Santiago Garcia,Rodriguez, Elena Garcia
, p. 2675 - 2686 (2007/10/03)
Acetylhydrazine, semicarbazide and methoxycarbonylhydrazine react with β-aminoenones to give regioselectively the corresponding N-acetyl- or N- carboxypyrazole derivatives. The reaction are highly regioselective and occurs via 5-hydroxypyrazolines which in several case can be isolated and characterized.