255901-50-9Relevant articles and documents
Indole derivative-proEDOT compound as well as preparation and application thereof
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Paragraph 0028; 0032-0033, (2020/12/30)
The invention relates to an indole derivative-proEDOT compound as well as preparation and application thereof. The indole derivative is taken as a central core of the compound, a compound 3, 4-(2, 2-dimethyl propylene dioxy) thiophene (proEDOT) is taken as a support arm, and the structure of the compound is shown as a formula (1). The indole derivative-proEDOT compound has the beneficial effects that (1), the Y-shaped material capable of easily forming the net structure is provided, a film is formed through electrochemical polymerization, the obtained film is uniform and shows a large specificsurface area, and good electrochromism and other electrochemical properties are shown; and (2), a film prepared by taking the compound as a monomer through electrochemistry can be randomly switched from yellow to green (0.9 V) and to gray (1.2 V), the optical contrast ratio is 20%-40%, the response time is 0.5-4s, and the compound shows relatively good spectral electrochemical stability in any waveband and has a good application prospect.
Triphenylamine-based dyes bearing functionalized 3,4- propylenedioxythiophene linkers with enhanced performance for dye-sensitized solar cells
Liang, Yanliang,Peng, Bo,Liang, Jing,Tao, Zhanliang,Chen, Jun
supporting information; experimental part, p. 1204 - 1207 (2010/06/13)
Chemical Equation Presented Introduction of modified 3,4-propylenedioxythiophene units into triphenylamine-based dyes is found to enhance light capturing, suppress dye aggregation, and remarkably retard charge recombination in dye-sensitized solar cells. Open circuit voltages of the as-synthesized dyes (~800 mV) are much higher than that with a thiophene congener (720 mV) under similar conditions as a result of self-passivation benefiting from their three-dimensional branched structures.