2560-56-7Relevant academic research and scientific papers
Crystal Multi-Conformational Control Through Deformable Carbon-Sulfur Bond for Singlet-Triplet Emissive Tuning
Wu, Hongwei,Chi, Weijie,Baryshnikov, Gleb,Wu, Bin,Gong, Yifan,Zheng, Dongxiao,Li, Xin,Zhao, Yanli,Liu, Xiaogang,?gren, Hans,Zhu, Liangliang
supporting information, p. 4328 - 4333 (2019/03/11)
Crystal-state luminophores have been of great interest in optoelectronics for years, whereas the excited state regulation at the crystal level is still restricted by the lack of control ways. We report that the singlet-triplet emissive property can be pro
Potassium Cryptate of a Macrobicyclic Ligand Featuring a Reducible Hexakis(phenylthio)benzene Electron-Acceptor Site
Mayor, Marcel,Lehn, Jean-Marie
, p. 2277 - 2285 (2007/10/03)
The synthesis and structural characterization of the macrobicyclic ligand 1 containing a reducible hexakis(phenylthio)benzene electron-acceptor site is described. It is based on the condensation of the tetraoxa-di-azamacrocycle 3 with a suitably functiona
THE THIOLATE ANION AS A NUCLEOPHILE. PART XIV. FURTHER REACTIONS OF TIN(II) ARENETHIOLATES
Jesudason, J. Joseph,Peach, Michael E.
, p. 357 - 362 (2007/10/02)
The reactions of tin(II) benzenethiolate in DMF with hexafluorobenzene, chloropentafluorobenzene and bromopentafluorobenzene have been compared.Replacement of fluorine and chlorine by the phenylthio group and protodebromination were observed.DMF was a better solvent than either ethylene glycol/pyridine mixture (1:2) or diglyme for the reaction.New products have been isolated and characterized from the reactions of tin(II) p-chlorobenzenethiolate with hexafluorobenzene, decafluorobiphenyl, octafluorotoluene and pentafluorobenzyl bromide.
THE THIOLATE ANION AS A NUCLEOPHILE. PART XIII. REACTIONS OF SOME TIN(II) AROMATIC THIOLATES
Hynes, Rosemary C.,Peach, Michael E.
, p. 129 - 134 (2007/10/02)
The reactions of tin(II) benzenethiolate and p-toluenethiolate with various fluoroaromatics in DMF have been studied.Replacement of some of the aromatic fluorines by the thiolate group was observed.The tin(II) aromatic thiolates are comparable in reactivity in these reactions with lead(II) benzenethiolate.All new compound have been characterized by elemental analysis, and NMR (H-1 and F-19) and mass spectroscopy.
