25626-89-5

Upstream product

• 2397-47-9 triethyl N-phenylphosphorimidate 
• 75-03-6 ethyl iodide 
• 103-69-5 N-ethyl-N-phenylamine 
• 762-04-9 phosphonic acid diethyl ester 
• 133827-73-3 trideuteromethyl phenylimidophosphate 
• 102968-99-0 tris(isopropyloxy)phenyliminophosphane 
• 54635-88-0 phenyl-imidophosphoric acid tributyl ester 
• 122-52-1 triethyl phosphite 
• 147672-01-3 C₁₂H₅⁽²⁾H₁₅NO₃P 
• 74-96-4 ethyl bromide 
• 1445-38-1 diethyl phenylphosphoramidate 

Downstream Products

• 73755-65-4 (OC₂H₅)2P(O)N(C₂H₅)C₆H₅(BF₃) 

Relevant academic research and scientific papers

Electrochemical phosphorylation of arenols and anilines leading to organophosphates and phosphoramidates

A practical phosphorylation for generating organophosphates and phosphoramidatesviaelectrochemical dehydrogenative cross-coupling of P(O)H compounds with arenols and anilines is disclosed. This method involves using inorganic iodide salts as both redox catalysts and electrolytes in an undivided cell without the addition of oxidants or bases. A preliminary mechanistic study suggests that radicals are not involved in this process. This method is green and eco-friendly and has good functional group tolerance, high yields and broad substrate scope, with the potential for practical synthesis.

A GC-MS imvestigation of the mechanism of imide-amide rearrangement

The products of imide-amide rearrangement of trialkyl (arylamido)phosphates were studied by the GC-MS method.An ionic chain mechanism was suggested for this reaction. - Key words: capillary gas chromatography, mass spetrometry, imide-amide rearrangement, trialkyl (arylimido)phosphates, ionic chain mechanism.

GC-MS STUDY OF THE IMIDE - AMIDE REARRANGEMENT

The imide - amide rearrangement of trialkyl arylimidophosphates by the action of catalytic amounts of boron trifluoride etherate proceeds at least partially by an intermolecular mechanism.Keywords: capillary gas-liquid chromatography/mass spectrometry, im

DIREKTSYNTHESE VON N,N-DIORGANYL-PHOSPHORSAEUREDIALKYLESTERAMIDEN AUS TRIALKYLPHOSPHITEN

Dialkyl N,N-Diorganylphosphoroamidates result in the reaction of trialkylphosphites with secondary amines and tetrachlormethane if amine hydrochlorides are used as catalysts.A reaction mechanism is proposed.Key words: N,N-Diorganylphosphoroamidates; trialkylphosphites; tetrachlormethane.