256397-88-3

Upstream product

• 158157-93-8 (E)-4-Benzyloxy-2-oxo-but-3-enoyl chloride 
• 935-04-6 benzyl vinyl ether 
• 179924-43-7 methyl trans-4-benzyloxy-2-oxo-3-butenoate 
• 164386-44-1 (R)-Phenyl-vinyloxy-acetic acid butyl ester 
• 207557-97-9 (4S,6S)-4-Benzyloxy-6-((R)-butoxycarbonyl-phenyl-methoxy)-5,6-dihydro-4H-pyran-2-carboxylic acid methyl ester 

Downstream Products

• 179924-50-6 (R)-1-phenyl-2-(α,α-diphenylbenzyloxy)ethyl-3,4-di-O-benzyl-2-deoxy-6-O-(α,α-diphenylbenzyl)-L-glucoside 
• 179924-49-3 (R)-1-phenyl-2-(α,α-diphenylbenzyloxy)ethyl-3-O-benzyl-2-deoxy-6-O-(α,α-diphenylbenzyl)-L-glucoside 
• 179924-47-1 (2S,3R,4S,6S)-3,4-Bis-benzyloxy-2-benzyloxymethyl-6-((R)-2-benzyloxy-1-phenyl-ethoxy)-tetrahydro-pyran 
• 179924-48-2 (R)-2-hydroxy-1-phenylethyl-3-O-benzyl-2-deoxy-L-glucoside 

Relevant academic research and scientific papers

A new synthetic approach toward (+)-ambruticin analogs: Preparation of a C10-C11 cis-isomer fragment

A new methodology has been applied to synthesize an isomer of the west part of (+)-ambruticin based on an efficient asymmetric de novo access to the A unit and sequential stereospecific reactions catalyzed by Pd0 for the construction of the B unit.

Chiral enol ethers in carbohydrate chemistry: De novo synthesis of protected L-2-deoxy hexoses

(3,4,6)Tri- and (3,4)-di-O-benzyl-2-deoxy-L-glucose 8 and 12 have been de novo synthesized in a convergent seven-step sequence involving asymmetric endo heterocycloaddition of the new heterodiene, methyl (E)-benzyloxymethylene pyruvate 2b with the O-vinyl mandelic ester (R)-(-)-3.