256408-45-4

Upstream product

• 144302-38-5 (R)-benzylidene-(2-methoxy-1-phenylethyl)amine 
• 75-03-6 ethyl iodide 

Downstream Products

• 131214-09-0 (2R,1'R)-2-<(1'-phenylpropyl)amino>-2-phenylethanol 
• 2941-20-0 1-phenylpropylamine 

Relevant academic research and scientific papers

Diastereoselective allylation and alkylation of optically active imines with metallic samarium and a catalytic amount of iodine

Barbier-type allylation and alkylation of optically active imines such as N-benzylidenevalinol methyl ether was performed with metallic samarium, a catalytic amount of iodine, and allyl or alkyl halides. This reaction proceeded in a highly diastereoselect

Asymmetric synthesis of allyl- and α-allenylamines from chiral imines and alkynes via (η2-imine)Ti(O-i-Pr)2 complexes

(Matrix presented) The reaction of a divalent titanium reagent Ti(O-i-Pr)4/2i-PrMgX with optically active arylaldimines derived from arylaldehydes and O-methylphenylglycinol provided, in a highly diastereoselective manner, chiral (η2-imine)Ti(O-i-Pr) 2 complexes, which in turn reacted with 1-alkynes or propargyl compounds to give optically active allyl- and α-allenylamines, respectively.