256416-34-9Relevant academic research and scientific papers
The dienolate [2,3]-Wittig rearrangement - Diastereoselective synthesis of highly functionalized tertiary alcohols
Hiersemann, Martin,Lauterbach, Christa,Pollex, Annett
, p. 2713 - 2724 (2007/10/03)
The [2,3]-Wittig rearrangement of dienolates generated from α-allyloxy- substituted α,β- and/or β,γ-unsaturated esters 4/5a-g has been investigated. The rearrangement proceeds with high yield and diastereoselectivity to afford 3-hydroxy-3-alkyloxycarbonyl
