256469-27-9

Basic information

• Product Name: 3-[2-(tert-butyl-dimethyl-silanyloxy)-ethyl]-2,2-dimethyl-cyclohex-3-enone
• Synonyms: 3-[2-(tert-butyl-dimethyl-silanyloxy)-ethyl]-2,2-dimethyl-cyclohex-3-enone
• CAS NO: 256469-27-9
• Molecular Weight: 282.498
• Mol File: 256469-27-9.mol

Chemical Properties

• CAS DataBase Reference: 3-[2-(tert-butyl-dimethyl-silanyloxy)-ethyl]-2,2-dimethyl-cyclohex-3-enone(CAS DataBase Reference)
• NIST Chemistry Reference: 3-[2-(tert-butyl-dimethyl-silanyloxy)-ethyl]-2,2-dimethyl-cyclohex-3-enone(256469-27-9)
• EPA Substance Registry System: 3-[2-(tert-butyl-dimethyl-silanyloxy)-ethyl]-2,2-dimethyl-cyclohex-3-enone(256469-27-9)

Safety Data

• Hazardous Substances Data: 256469-27-9(Hazardous Substances Data)

Upstream product

• 256469-23-5 6,6-dimethyl-1,4-dioxaspiro[4.5]dec-7-en-7-yl trifluoromethanesulfonate 
• 256469-25-7 2-(6,6-dimethyl-1,4-dioxa-spiro[4.5]dec-7-en-7-yl)-ethanol 
• 256469-24-6 6,6-dimethyl-7-ethenyl-1,4-dioxaspiro[4.5]dec-7-ene 
• 14782-52-6 ethylene glycole monoacetal of 2,2-dimethylcyclohexane-1,3-dione 
• 18162-48-6 tert-butyldimethylsilyl chloride 
• 256469-26-8 3-(2-hydroxyethyl)-2,2-dimethylcyclohex-3-en-1-one 

Downstream Products

• 256469-30-4 1-but-3-enyl-3-[2-(tert-butyl-dimethyl-silanyloxy)-ethyl]-2,2-dimethyl-cyclohex-3-enol 
• 256469-32-6 1-cyclohex-2-enylmethyl-3-(2-hydroxy-ethyl)-2,2-dimethyl-cyclohex-3-enol 
• 256469-39-3 1-cyclohex-2-enylmethyl-3-(2-iodo-ethyl)-2,2-dimethyl-cyclohex-3-enol 
• 256469-40-6 1-but-3-enyl-3-(2-iodo-ethyl)-2,2-dimethyl-cyclohex-3-enol 
• 256469-35-9 (5-cyclohex-2-enylmethyl-5-hydroxy-6,6-dimethyl-cyclohex-1-enyl)-acetaldehyde 
• 256469-33-7 1-but-3-enyl-3-(2-hydroxy-ethyl)-2,2-dimethyl-cyclohex-3-enol 
• 256469-38-2 (5-but-3-enyl-5-hydroxy-6,6-dimethyl-cyclohex-1-enyl)-acetaldehyde oxime 
• 256469-44-0 1-allyl-2,2-dimethyl-3-(2-nitro-ethyl)-cyclohex-3-enol 
• 256469-41-7 1-allyl-3-(2-iodo-ethyl)-2,2-dimethyl-cyclohex-3-enol 
• 256469-36-0 (5-but-3-enyl-5-hydroxy-6,6-dimethyl-cyclohex-1-enyl)-acetaldehyde 
• 256469-31-5 1-allyl-3-[2-(tert-butyl-dimethyl-silanyloxy)-ethyl]-2,2-dimethyl-cyclohex-3-enol 
• 256469-29-1 3-[2-(tert-butyl-dimethyl-silanyloxy)-ethyl]-1-cyclohex-2-enylmethyl-2,2-dimethyl-cyclohex-3-enol 

Relevant articles and documents

Studies directed toward the synthesis of taxanes: Evaluation of the B- ring formation by an intramolecular nitrile oxide cycloaddition

Several models for the formation of the 8-membered B-ring of taxanes by an intramolecular nitrile oxide [3+2] cycloaddition were prepared from the monoacetal of 2,2-dimethylcyclohexane-1,3-dione (5). The nitrile oxides were then generated under high-dilut