256472-78-3Relevant academic research and scientific papers
Synthesis of [carbonyl-14C]-4-benzoylbenzoic acid, a photolabelling reagent
Gomis, Jean-Marie,Santolini,Andre,Noel
, p. 1175 - 1182 (1999)
[carbonyl-14C]-4-Benzoylbenzoic acid, a photolabelling reagent, was synthesised with high specific activity in 57% radioactive yield from [carboxyl-14C]-benzoic acid. Radioactive synthesis allowed elucidation of the mechanism of a previous unlabelled synthesis using benzoic acid, methyl ester. An improvement in the experimental conditions led to a new synthesis of radioactive benzoylbenzoic derivatives with good yield.
Synthesis of a [14C]-labelled photoactivatable cyclic tetrapeptide: [Carbonyl-14C]-4-benzoylbenzoyl MeSer1-tentoxin
Gomis,Santolini,Cavelier,Verducci,Pinet,Andre,Noel
, p. 323 - 330 (2007/10/03)
The synthesis of a new photochemical probe for labelling tentoxin 1 binding sites in the soluble part of chloroplast F0F1 ATPsynthase is described. [Carbonyl-14C]-4-benzoylbenzoyl MeSer1-tentoxin 6 was synthesised by coupling MeSer1-tentoxin 2 with [carbonyl-14C]-4-benzoylbenzoic acid 3, itself obtained by coupling [1-14C]-benzoyl chloride with the dilithio derivative of 4-bromobenzoic acid (9). Photolysis of the probe in methanolic solution occurs readily upon irradiation with UV light at 366 nm.
