256494-25-4

Upstream product

• 867-13-0 diethoxyphosphoryl-acetic acid ethyl ester 
• 112897-03-7 3-(tert-butyldiphenylsilyloxy)-1-propanal 
• 127047-71-6 3-(tert-butyldiphenylsilyloxy)propan-1-ol 
• 135006-32-5 4-tert-butyldiphenylsilyloxy-1-butene 
• 58479-61-1 tert-butylchlorodiphenylsilane 
• 1099-45-2 ethyl (triphenylphosphoranylidene)acetate 

Downstream Products

• 562823-69-2 (2R,3S)-5-(tert-Butyl-diphenyl-silanyloxy)-2,3-dihydroxy-pentanoic acid ethyl ester 
• 1422347-14-5 ((E,3S,6S)-6-methoxy-3, 5-dimethylnona-4, 8-dienyloxy)(tert-butyl)diphenylsilane 
• 1422347-12-3 (4S,7S,E)-9-(tert-butyldiphenylsilyloxy)-5,7-dimethylnona-1,5-dien-4-ol 
• 256494-42-5 (3R,4R,5R)-tert-butyl 3-(3-(2-(2,2-dimethyl-1,1-diphenyl-1-silapropoxy)ethyl)(2-oxiranyl))-3-hydroxypropanoate 
• 256494-33-4 (2S,3R)-3-(2-(2,2-dimethyl-1,1-diphenyl-1-silapropoxy)ethyl)oxirane-2-carbaldehyde 
• 256494-32-3 (2R,3S)-3-(2-(2,2-dimethyl-1,1-diphenyl-1-silapropoxy)ethyl)oxirane-2-carbaldehyde 
• 172691-20-2 (3S,4S,5S)-tert-butyl 3-(3-(2-(2,2-dimethyl-1,1-diphenyl-1-silapropoxy)ethyl)(2-oxiranyl))-3-hydroxypropanoate 
• 127758-12-7 (2R,3R)-(3-(2-(2,2-dimethyl-1,1-diphenyl-1-silapropoxy)ethyl)-2-oxiranyl)methan-1-ol 
• 116003-84-0 (2S,3S)-(3-(2-(2,2-dimethyl-1,1-diphenyl-1-silapropoxy)ethyl)-2-oxiranyl)methan-1-ol 
• 423118-12-1 tert-butyl-diphenyl-(5-vinyloxy-pent-3-enyloxy)-silane 
• 562823-66-9 (2S,3S,5S)-6-((4S,5S)-5-Benzyloxymethyl-2,2-dimethyl-[1,3]dioxolan-4-yl)-5-(tert-butyl-dimethyl-silanyloxy)-2,3-dihydroxy-hexanoic acid methyl ester 
• 562823-65-8 (Z)-(S)-6-((4S,5S)-5-Benzyloxymethyl-2,2-dimethyl-[1,3]dioxolan-4-yl)-5-(tert-butyl-dimethyl-silanyloxy)-hex-2-enoic acid methyl ester 
• 562823-57-8 [2-((4S,5S)-5-Benzyloxymethyl-2,2-dimethyl-[1,3]dioxolan-4-yl)-ethoxy]-tert-butyl-diphenyl-silane 
• 562823-70-5 (4R,5S)-5-[2-(tert-Butyl-diphenyl-silanyloxy)-ethyl]-2,2-dimethyl-[1,3]dioxolane-4-carboxylic acid ethyl ester 

Relevant academic research and scientific papers

Enantioselective synthesis of the C5-C23 segment of biselyngbyaside

Stereo and enantioselective synthesis of C5-C23 fragment of cytotoxic marine natural product biselyngbyaside is achieved using E-selective methyl lithium addition onto enyne, Crimmin's acetate aldol reaction, Sharpless asymmetric epoxidation, and Julia-Kocienski olefination as the key steps.

Synthesis of the FG ring fragment of pectenotoxins 1-9

The synthesis of the FG ring fragment common to pectenotoxins 1-9 is reported.The successful, convergent synthesis relied on high yielding routes to access two key intermediates; aldehyde 1 and phosphonium salt 2.A Z-selective Wittig reaction gave access

Synthesis of the FG fragment of the pectenotoxins

The synthesis of the FG subunit of the pectenotoxins is reported herein. The synthesis hinges on the preparation of an appropriately functionalized acyclic precursor using a Z-selective Wittig reaction. Further elaboration using two sequential cyclization

A total synthesis of the antitumour macrolide rhizoxin D

An enantioselective synthesis of rhizoxin D (2), isolated from the plant pathogenic fungus Rhizopus chinensis, is described. The overall strategy is based on elaboration of the δ-lactone-substituted vinyl stannane 7 and the phosphonate-substituted vinyl i

Attempt to rationalize the diastereoselectivity in the addition of ester enolate to optically active α,β-epoxyaldehydes

Aldol condensations on α,β-epoxyaldehyde having a remote alkoxy group have been realized. A rationalization of the outcome of this condensation is discussed, relying on the dominant conformers revealed by molecular modeling of anti and syn γ,δ-epoxy β-hyd

Die Struktur von Maitotoxin - II: Konfiguration der C135-C142-Seitenkette und absolute Konfiguration des gesamten Molekuels

Keywords: Asymmetrische Synthesen; Strukturaufklaerung; Maitotoxin; Naturstoffe; NMR-Spektroskopie